58510-41-1

Basic information

• Product Name: di-O-benzoyl-1,2-O-(α-methoxybenzylidene)-α-D-ribofuranose
• Synonyms: di-O-benzoyl-1,2-O-(α-methoxybenzylidene)-α-D-ribofuranose
• CAS NO: 58510-41-1
• Molecular Weight: 476.483
• Mol File: 58510-41-1.mol

Chemical Properties

• CAS DataBase Reference: di-O-benzoyl-1,2-O-(α-methoxybenzylidene)-α-D-ribofuranose(CAS DataBase Reference)
• NIST Chemistry Reference: di-O-benzoyl-1,2-O-(α-methoxybenzylidene)-α-D-ribofuranose(58510-41-1)
• EPA Substance Registry System: di-O-benzoyl-1,2-O-(α-methoxybenzylidene)-α-D-ribofuranose(58510-41-1)

Safety Data

• Hazardous Substances Data: 58510-41-1(Hazardous Substances Data)

Upstream product

• 6974-32-9 1-O-acetyl-2,3,5-tri-O-benzoyl-β-D-ribofuranose 
• 29706-90-9 β-D-2,3,5-tri-O-benzoylribofuranosyl chloride 
• 4637-24-5 N,N-dimethyl-formamide dimethyl acetal 

Downstream Products

• 121836-01-9 C₃₂H₃₂O₁₀ 
• 2924-34-7 2,3,5-tri-O-benzoyl-β-D-ribofuranosyl fluoride 
• 7473-45-2 1-O-methyl-D-ribofuranose 
• 138328-71-9 (2'R)-3'-bromo-2'-hydroxypropyl tri-O-benzoyl-β-D-ribofuranoside 
• 138328-70-8 (2'S)-2',3'-dihydroxypropyl tri-O-benzoyl-β-D-ribofuranoside 
• 4099-85-8 ((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl)methanol 
• 38838-05-0 1-O-methyl-2,3-O-isopropylidene-5-bromo-5-deoxy-β-D-ribofuranoside 
• 103411-70-7 (S)-2',3'-isopropylidenedioxypropyl tri-O-benzoyl-β-D-ribofuranoside 
• 52783-53-6 methyl 2,3,3'-tri-O-benzoyl-β-D-apiofuranoside 

Relevant articles and documents

THE SYNTHESIS OF (R)-2',3'-DIHYDROXYPROPYL 5-DEOXY-5-DIMETHYLARSINOYL-β-D-RIBOSIDE, A NATURALLY-OCCURING, ARSENIC-CONTAINING CARBOHYDRATE

The synthesis of (R)-2',3'-dihydroxypropyl 5-deoxy-5-dimethylarsinoyl-β-D-riboside is reported.

The Synthesis of (R)-2',3'-Dihydroxypropyl 5-Deoxy-5-dimethylarsinyl-β-D-riboside, a Naturally Occurring Arsenic-Containing Carbohydrate

The synthesis of the title compound, isolated from the brown kelp (Ecklonia radiata) or the giant clam (Tridacna maxima), is reported.Glycosidation of 1-O-acetyl-2,3,5-tri-O-benzoyl-β-D-ribose, either directly with (S)-1,2-di-O-benzylglycerol or via the derived orthoester with (S)-1,2-O-isopropylideneglycerol, led to two fully protected glycerol β-D-ribofuranosides.Subsequent chemical manipulations led to a common intermediate having a free hydroxy group at C 5 of the D-ribose residue.Replacement of this hydroxy group by a chlorine atom allowed the introduction of the dimethylarsinyl group at C 5 in a two-step procedure, and removal of protecting groups provided the natural product.