29266-28-2

Upstream product

• 36744-45-3 exo-3-Hydroxybicyclo<2.2.1>heptan-exo-2-carboxamid 
• 94078-86-1 exo-3-(Aminomethyl)bicyclo<2.2.1>heptan-exo-2-ol 
• 825-60-5 benzimidic acid ethyl ester 

Downstream Products

• 94078-84-9 (1S,2R,7R,8R)-4-(3-Chloro-phenyl)-3-oxa-5-aza-tricyclo[6.2.1.0^2,7]undec-4-ene 
• 94098-57-4 (1S,2R,7R,8R)-4-(4-Chloro-phenyl)-3-oxa-5-aza-tricyclo[6.2.1.0^2,7]undec-4-ene 
• 94078-85-0 (1S,2R,7R,8R)-4-p-Tolyl-3-oxa-5-aza-tricyclo[6.2.1.0^2,7]undec-4-ene 
• 100460-89-7 rel-(1R,2S,4S,5R,9R,10S)-5-chloro-4-phenyl-6-oxo-7-aza-3-oxatetracyclo<8.2.1.0^2,9.0^4,7>tridecane 
• 100460-95-5 rel-(1S,2S,4R,11R,12R)-7-chloro-6-chloromethyl-8-oxo-4-phenyl-9-aza-3,5-dioxatetracyclo<10.2.1.0^2,11.0^4,9>pentadec-6-ene 
• 100460-91-1 rel-(1R,2S,4S,9R,10S)-5,5-dichloro-4-phenyl-6-oxo-7-aza-3-oxatetracyclo<8.2.1.0^2,9.0^4,7>tridecane 
• 94078-86-1 exo-3-(Aminomethyl)bicyclo<2.2.1>heptan-exo-2-ol 
• 65-85-0 benzoic acid 

Relevant academic research and scientific papers

Stereochemical Studies, 77. - Saturated Heterocycles, 64 - Synthesis of Saturated Methylene-Bridged 1,3-Benzoxazines

The aminomethylbicyclanol 3, obtained from the cycloadduct 4 of norbornene (1) and trichloroacetyl isocyanate, furnished the 1,3-oxazin-2-one 7, 1,3-oxazine-2-thione 8 and 1,3-oxazines 2a-d.The exo-exo- (10, 12) and endo-endo-1,3-oxazin-4-ones (11, 13) were prepared from the 3-hydroxy-2-carboxamides 5 and 9.Structure of these rigid tricyclic systems were proved by 1H and 13C NMR spectroscopy.