2929-96-6

Usage

Uses

Used in Rubber and Plastics Industry:
2,2'-Thiobis(4-Methylphenol) is used as a stabilizer in the manufacturing of rubber and plastics for its ability to prevent degradation from heat and oxygen exposure, ensuring the longevity and quality of these materials.
Used in Synthetic Fibers Production:
In the production of synthetic fibers, 2,2'-Thiobis(4-Methylphenol) is used as a stabilizer to protect the fibers from oxidative damage, enhancing their durability and performance.
Used in Adhesives and Coatings Industry:
2,2'-Thiobis(4-Methylphenol) is utilized as an antioxidant in the formulation of adhesives and coatings to prevent oxidation and maintain the integrity of these products over time.
Used in Medical and Pharmaceutical Industries:
Due to its antioxidant properties and ability to protect against oxidative stress, 2,2'-Thiobis(4-Methylphenol) has potential applications in the medical and pharmaceutical industries, where it can contribute to the development of treatments and therapies that address oxidative stress-related conditions.

Upstream product

• 106-44-5 p-cresol 
• 27725-15-1 2-(2-hydroxy-5-methylphenylsulfinyl)-4-methylphenol 
• 161721-73-9 C₁₄H₁₂O₂S 

Downstream Products

• 133786-64-8 2-<3-<3-(3-bromo-5-methylsalicyl)-5-methylsalicyl>-2-hydroxy-5-methylphenylthio>-4-methylphenol 
• 133785-84-9 2-<3-<3-(2-hydroxy-5-methylphenylthio)-5-methylsalicyl>-2-hydroxy-5-methylphenylthio>-4-methylphenol 
• 133785-82-7 2-<3-<3-(2-hydroxy-5-methylphenylthio)-2-hydroxy-5-methylphenylthio>-2-hydroxy-5-methylphenylthio>-4-methylphenol 
• 1174233-07-8 thiobis[5-methyl-3-(4-bromophenyl(2-pyrimidinylamino)methyl)-2-phenol] 
• 1174233-05-6 thiobis[5-methyl-3-(4-methoxyphenyl(2-pyrimidinylamino)methyl)-2-phenol] 
• 1174233-03-4 thiobis[5-methyl-3-(phenyl(2-pyrimidinylamino)methyl)-2-phenol] 
• 1174233-12-5 thiobis[5-methyl-3-(4-chlorophenyl(2-pyrimidinylamino)methyl)-2-phenol] 
• 1174233-04-5 thiobis[5-methyl-3-(4-methylphenyl(2-pyrimidinylamino)methyl)-2-phenol] 
• 1174233-08-9 thiobis[5-methyl-3-(3-bromophenyl(2-pyrimidinylamino)methyl)-2-phenol] 
• 133785-86-1 2-<3-<3-(2-hydroxy-5-methylphenylthio)-5-methylsalicyl>-5-methylsalicyl>-4-methylphenol 
• 133785-85-0 2-<3-<3-(5-methylsalicyl)-2-hydroxy-5-methylphenylthio>-5-methylsalicyl>-4-methylphenol 
• 882304-68-9 2,2'-sulfinyl bis[methy(4-methylphenoxyacetate)] 
• 942290-31-5 2,2'-thio-bis[4-methyl-(2-nitrophenoxy)phenyl] ether 
• 133786-61-5 3-(2-hydroxy-5-methylphenylthio)-2-hydroxy-5-methylbenzyl alcohol 

Relevant academic research and scientific papers

A vanadyl(V) complex with a pincer-type thiobis(phenolate) and an acetylacetonate co-ligand, VO(tbp)(acac)

A new vanadyl(V) complex with the tridentate, pincer-type O,S, O-ligand thiobis(phenolate), tbp, was synthesized from the reaction of vanadium(IV) oxide bis(acetylacetonate), VO(acac)2, and 2,2′-thio-bis(4- methylphenol), H2tbp, in r

Synthesis of some new dimers as constructive of nano machines

In this research work, a part of nano machines is synthesized, based on interlocked macrocycle named rotaxanes, pseudorotaxanes, knots and catenanes which constitute any passive or active structure capable of actuation, mesoscale molecular electronic devi

Synthesis of some new ligands as drug carrier

In this research work, the preparation of new biscrown ether and lariat ether compounds as cationic and molecular acceptor are reported. For this purpose first, sulfoxide (1) was prepared by reaction of p-cresol with SOCl 2 in 65 % yield. Then

Efficient routes for the synthesis of dinaphthosulfide (BINOL Derivatives) and dibenzosulfide aza podands containing ethanolamine

Four new dinaphthosulfide and dibenzosulfide aza podands were synthesized. The synthesis of these podands was performed under three different reaction conditions: 1) diester, K2CO3, methanol, and RT; 2) diester, ethanolamine, and microwave (MW); and 3) diacid dichloride, ethanolamine, Et3N, CH2Cl2, RT. Two kinds of diester (dinaphthosulfide and dibenzosulfide) were used for the preparation of dihydroxy podands. These dihydroxy podands were reacted with thionyl chloride to afford dichloro podands. The second route gave excellent yields of dihydroxy podands. Dichloro podands are more soluble than dihydroxy podands in conventional solvents such as methanol, chloroform, and acetonitrile.

Spectrophotometric study of complexation of Tri-Aza dibenzosulfide and dibenzosulfoxide macrocyclic compounds with heavy metal ions

The complexation reactions between 7,10,13-triaza-1-thia-4,16-dioxa-20,24- dimethyl-2,3;17,18-dibenzo-cyclooctadecane-6,14-dione (TTD) and 7,10,13-triaza-1-sulfoxo-4,16-dioxa-20,24-dimethyl-2,3;17,18-dibenzo- cyclooctadecane-6,14-dione (TSD) macrocycles w

The synthesis and characterization of novel dibenzosulfide diamine and the application in the determination of heavy metals

New 2,2′-thio-bis [4-methyl (2-amino phenoxy) phenyl ether] (IV) was synthesized. The structure of this compound was confirmed on IR, 1H, and 13C NMR data. A simple, efficient, and sensitive procedure is described for the spectrophot

Synthesis and crystal structure determination of 2,2′-sulfinyl-bis(4- methyl phenol) and 2,2′-thio-bis(4-methyl phenol)

2,2′-Sulfinyl-bis(4-methyl phenol) 3 and it's thio derivative have been synthesized in this work. The reduction process of sulfoxide 3 to its thio derivative 5 was accomplished in the presence of Zn/AcOH/SiO2, under microwave irradiation. The s

New method for the preparation of o-aryloxyphenols: Pummerer-type rearrangement of ano-hydroxyaryl sulfoxide

A facile two-step preparation of o-aryloxyphenols is described in which the key step is the intramolecular trapping of an α-keto sulfonium salt prepared by Pummerer rearrangement of a symmetrical o-hydroxyaryl sulfoxide to give an orthoquinone mono(monoth

Synthesis and Inclusion Properties of Sulfur-Bridged Analogs of Acyclic Phenol-Formaldehyde Oligomers

A series of compounds in which a part or all of the methylene bridges of acyclic p-methyl- and p-t-butylphenol-formaldehyde tetramers were replaced by sulfur bridge(s) was synthesized.It was found that though the sulfur-bridged tetramers formed crystalline host-guest complexes with a variety of organic compounds, they were different from the parent tetramers regarding their inclusion behavior.The number and position of the sulfur bridge(s), as well as the p-substituent of phenol in the tetramers, had a great influence upon the inclusion property.The thermal stability of complexes of the sulfur-bridged tetramers (SSS-a,b) with benzene, as estimated from their thermal dissociation rates, are lower than those of the parent tetramers (CCC-a,b).

Rearrangements and decompositions of thiobisphenols

2,2′-, 2,4′- and 4,4′-Monothiobisphenol separately rearrange in phenol at 180° in the presence of sodium hydroxide to give similar mixtures containing only 2,2′-, 2,4′- and 4,4′-monothiobisphenol in the approximate ratio, 45:45:10. The rearrangements appear to be intermolecular and they are interpreted in terms of polar processes which lead initially to the formation of o- and p-monothiobenzoquinones. 2,2′-Dithiobisphenol, 4,4′-dithiobisphenol and 4,4′-trithiobisphenol under similar conditions are desulphurated with the evolution of hydrogen sulphide also to give mixtures containing only 2,2 - 2,4′- and 4,4′-monothiobisphenol whilst 3,3′-dithiobisphenol is stable in alkaline phenol even after long periods at 180°. Similar initial heterolyses to o- and p-monothiobenzoquinones are suggested as sources of the monothiobisphenols and displacements of sulphide- or hydrosulphide-ions from intermediate benzeneperthiolate ions by carbanions derived from phenol are suggested as sources of the hydrogen sulphide.