293295-78-0Relevant academic research and scientific papers
trans-chloro(2-nitrobenzenethiolato-S)bis(triphenylphosphine-P)palladium(II) monoacetone solvate
Aupers, John H.,Ferguson, George,Glidewell, Christopher,Low, John N.,Wardell, James L.
, p. 945 - 947 (2000)
Molecules of the title compound, [PdCl(C6H4NO2S)(PPh3)2]·-C3H6O, exhibit a slight distortion from exact planarity at the Pd atom towards tetrahedral, with P-Pd-P and Cl-Pd-S angles of 174.98 (3) and 174.19 (3)°, respectively. The Pd-Cl and Pd-S bonds are, respectively, long [2.3550 (11) angstroms] and short [2.3020 (12) angstroms] for their types; the S-C bond is also very short [1.744 (4) angstroms]. The solvating acetone molecule is linked to one of the phosphine ligands by means of a C-H···O hydrogen bond.
