29346-31-4Relevant articles and documents
DIRECTED CLEAVAGE OF CARBON-TIN BONDS BY PALLADIUM
Suggs, J. William,Lee, Ken. S.
, p. 297 - 310 (2007/10/02)
The ligands 8-(trimethylstannyl)methylquinoline, n-Bu3Sn(CH2)3NMe2 and Ph3Sn(CH2)3NMe2 Ph3Sn(CH2)3NMe2 react with (C6H5CN)2PdCl2 to give five-membered palladium chelates, in which the nitrogen atom was able to direct palladium insertion into a specific carbon-tin bond.The X-ray crystal structure of the simple chelate 2 is presented.