29412-46-2Relevant articles and documents
Etude de la fixation du groupe tertiaire gem-dimethylpropynyle HCCC(CH3)2 par voie organometallique; applications
Barbot, F.,Miginiac, Ph.
, p. 249 - 261 (1992)
Organometallics (CH3)2C=C=CHM (M = MgBr, Al2/3Br, ZnBr) are easily prepared from the tertiary bromide (CH3)2C(Br)CCH.They often react to give only acetylenic products but, with some reagents, a mixture of acetylenic and allenic compounds is obtained.