Etude de la fixation du groupe tertiaire gem-dimethylpropynyle HCCC(CH3)2 par voie organometallique; applications

DOI: 10.1016/0022-328X(92)80204-B

Source and publish data:

Journal of Organometallic Chemistry p. 249 - 261 (1992)

Update date:2022-08-03

Topics:

Authors:

Barbot, F.

Miginiac, Ph.

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Article abstract of DOI:10.1016/0022-328X(92)80204-B

Organometallics (CH3)2C=C=CHM (M = MgBr, Al_2/3Br, ZnBr) are easily prepared from the tertiary bromide (CH3)2C(Br)C<*>CH.They often react to give only acetylenic products but, with some reagents, a mixture of acetylenic and allenic compounds is obtained.

Full text of DOI:10.1016/0022-328X(92)80204-B

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