29443-56-9Relevant academic research and scientific papers
Studies on the Synthesis of Heterocyclic Compounds. XVI. Cleavage of 1,3-Benzodioxoles and -Benzoxathioles by Sodium Iodide-Acyl Chloride
Corda, Luciana,Fadda, Anna Maria,Maccioni, Antonio,Maccioni, Anna Maria,Podda, Gianni
, p. 311 - 314 (2007/10/02)
The cleavage reaction of ethereal and thioethereal bonds with sodium iodide and acyl chloride has been studied.In all the 1,3-benzodioxoles and -benzoxathioles studied, the opening of the heterocyclic ring with formation of 1,2-diacetoxybenzene or 2-hydroxythiophenol diacetic acid ester and gem-diiodoalkanes and iodoalkenes has been observed.The structure of newly prepared compounds has been determined by analytical and spectroscopic data or comparison with authentic samples.
Copper(I) Iodide-Assisted Halogen Exchange at Vinylic Positions. Conversion of Vinyl Vinylene, and Vinylidene Bromides to the Corresponding Iodo Analogs
Suzuki, Hitomi,Aihara, Mie,Yamamoto, Hidetoshi,Takamato, Yuuko,Ogawa, Takuji
, p. 236 - 238 (2007/10/02)
The title bromo olefins undergo the copper(I) iodide-mediated exchange with iodide ion in hot hexamethylenephosphoric triamide to give the corresponding iodo analogs in moderate to good yield.
