295-40-9 Usage
Uses
Used in Chemical Industry:
1,4,8,11-Tetraoxacyclotetradecane is used as a chelating agent for the selective complexation of metal ions. Its ability to form stable complexes with specific metal ions makes it a valuable component in the synthesis of metal-organic frameworks and other coordination compounds.
Used in Pharmaceutical Industry:
1,4,8,11-Tetraoxacyclotetradecane is used as a component in the formulation of certain drugs, particularly those that require controlled release or targeted delivery. Its unique structure allows for the encapsulation or conjugation of drug molecules, enhancing their stability, solubility, and bioavailability.
Used in Material Science:
1,4,8,11-Tetraoxacyclotetradecane is used in the preparation of single-wall carbon nanotubes (SWNT). Its ability to interact with and stabilize SWNTs makes it a valuable additive in the production of these advanced materials, which have potential applications in electronics, energy storage, and other high-tech industries.
Used in Environmental Applications:
1,4,8,11-Tetraoxacyclotetradecane can be used as an extractant in the separation and purification of various compounds, particularly in the field of environmental remediation. Its selective complexation properties enable the efficient removal of contaminants from water and other media.
Check Digit Verification of cas no
The CAS Registry Mumber 295-40-9 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 2,9 and 5 respectively; the second part has 2 digits, 4 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 295-40:
(5*2)+(4*9)+(3*5)+(2*4)+(1*0)=69
69 % 10 = 9
So 295-40-9 is a valid CAS Registry Number.
295-40-9Relevant academic research and scientific papers
Kobiro, Kazuya,Matsuoka, Toshihiro,Takada, Shigeki,Kakiuchi, Kiyomi,Tobe, Yoshito,Odaira, Yoshinobu
, p. 713 - 714 (1986)
Didecalino-14-crown-4 has been synthesized and found to have the conspicuous extractability as well as selectivity for lithium ion.
Synthesis of Substituted 14-Crown-4 Compounds
Czech, Bronislaw P.,Zazulak, Wolodymyr,Kumar, Anand,Olsher, Uriel,Feinberg, Hadar,et al.
, p. 1389 - 1400 (2007/10/02)
Seventeen new substituted 14-crown-4 derivatives 3-10, 35-40, 42, 45 and 46 are described.A series of nine compounds 2-10 with two, three or four substituents in the 6- and/or 13-positions was synthesized in good yields from the appropriate diols and ditosylates using improved cyclization conditions.The solid state structures of 6,6,13,13-tetra(benzyloxymethyl)-14-crown-4 (8) and lithium thiocyanate complexes of trans- and cis-6,13-bis(spiro-2,2-dichlorocyclopropyl)-14-crown-4 (45) and (46), respectively, have been determined.
Molecular design of crown ethers. VII.1 syntheses and cation selectivities of unsubstituted 12- To 16-crown-4
Liu, Yu,Inoue, Yoshihisa,Hakushi, Tadao
, p. 3044 - 3046 (2007/10/02)
Solvent extraction of aqueous alkali and some heavy metal picrates with the title compounds showed that, with most cations except for Li+, Na+, and Ag+, the extractability decreases monotonically as the ring size increases from 12 to 16. However, 14-crown-4 showed the highest extractability and selectivity for Li+ over the larger alkali metals, while 15-crown-4 exhibited the highest Ag+/Tl+ selectivity.
