67439-82-1Relevant articles and documents
Nae,Jagur-Grodzinski
, p. 489,490 (1977)
Design, synthesis, and characterization of peptide nanostructures having ion channel activity
Biron, Eric,Otis, Francois,Meillon, Jean-Christophe,Robitaille, Martin,Lamothe, Julie,Van Hove, Patrick,Cormier, Marie-Eve,Voyer, Normand
, p. 1279 - 1290 (2007/10/03)
We report the synthesis and the functional studies of multiple crown α-helical peptides designed to form artificial ion channels. The approach combines the versatility of solid phase peptide synthesis, the conformational predictability of peptidic molecul
Substituted diether diols by ring-opening of carbocyclic and stannylene acetals
Martinez-Bernhardt, Rolando,Castro, Peter P.,Godjoian, Gayane,Gutierrez, Carlos G.
, p. 8919 - 8932 (2007/10/03)
Reduction of malonaldehyde bis(ethylene and propylene acetals) with borane or monochloroborane produces diether diols 1 and 2 in high yield. Similar reduction of glyoxal his(ethylene acetals) has only limited utility for the preparation of tetrasubstituted triethylene glycols 3. Organotin chemistry is complementary: stannylene acetals prepared from disubstituted vicinal diols can be alkylated with half an equivalent of 1,2-dibromoethane to produce tetrasubstituted triethylene glycols 3, or with two equivalents of 2-chloroethanol to produce disubstituted triethylene glycols 4.