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"2,2',4,4',6,6'-hexapyrrolidin-1-yl-1,1'-bicyclohexadienylium diperchlorate" is a complex organic compound with the chemical formula C36H48N6?2ClO4. It is a derivative of the parent compound 1,1'-biphenyl, where six pyrrolidine rings are attached to the 2,2', 4,4', 6, and 6' positions. The compound is characterized by its unique structure, which features a bicyclohexadienylium core with pyrrolidine substituents. It is typically synthesized through a series of chemical reactions and is used in various applications, including as a reagent in organic synthesis and as a building block for more complex molecules. The diperchlorate salt form indicates the presence of two perchlorate ions (ClO4-), which serve to balance the charge of the positively charged hexapyrrolidin-1-yl-1,1'-bicyclohexadienylium cation. 2,2',4,4',6,6'-hexapyrrolidin-1-yl-1,1'-bicyclohexadienylium diperchlorate is of interest to researchers in the field of organic chemistry due to its potential applications and the challenges it presents in synthesis and characterization.

29531-65-5

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29531-65-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 29531-65-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,9,5,3 and 1 respectively; the second part has 2 digits, 6 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 29531-65:
(7*2)+(6*9)+(5*5)+(4*3)+(3*1)+(2*6)+(1*5)=125
125 % 10 = 5
So 29531-65-5 is a valid CAS Registry Number.

29531-65-5Relevant academic research and scientific papers

Aminobenzenes, 21. - Electron Transfer in the Reactions of Halogeno ?-complexes of 1,3,5-Tris(1-pyrrolidinyl)benzene with Nucleophiles

Effenberger, Franz,Baeuerle, Peter,Seufert, Walter,Stohrer, Wolf-Dieter

, p. 193 - 200 (2007/10/02)

Iodo, bromo, chloro , and thiocyanato ?-complexes 4, accessible as crystalline compounds from 1,3,5-tris(1-pyrrolidinyl)benzene (1) with halogens and dirhodan, respectively, react with nucleophiles or bases under dehalogenation, deprotonation, dimerization, or H ?-complex formation.The product formation depends on the redox potentials of the ?-complexes ( acceptors) and the nucleophiles ( donors) , on the leaving tendency of the substituents on C-1 of the ?-complexes, and on the reaction time.The unexpected reactions are interpreted by an electron transfer from the nucleophile Y to the ?-complex A+ to give the radical A., a subsequent heterolytic dissociation to the 1,3,5-tris(1-pyrrolidinyl)benzene radical cation C+., and its follow-up reactions (addition of nucleophiles, dimerization, and H abstaction).The H ?-complex 6 results as the most stable final product after long reaction times because of its lowest acceptor properties and poor nucleofugal leaving tendency of a hydride ion.

Aminobenzenes. 19. Dimeric ?-complexes: Intermediates in the Oxidative Dimerization of Aromatics

Effenberger, Franz,Mack, Karl-Ernst,Niess, Rolf,Reisinger, Friedrich,Steinbach, Adalbert,et al.

, p. 4379 - 4386 (2007/10/02)

Dimeric ?-complexes 2, postulated intermediates in the oxidative dimerization of aromatics, were obtained by oxidation of tripyrrolidin-1-ylbenzenes 1a-f with silver nitrate.Treatment of 2 with strong base gave biphenyls 4.In solution, especially under th

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