16857-93-5

Upstream product

• 70746-80-4 1-Brom-2,4,6-tris(1-pyrrolidinyl)cyclohexadienylium-bromid 
• 70746-90-6 C₁₉H₂₇N₄S⁽¹⁺⁾*CNS^(1-) 
• 122408-37-1 1-Iod-2,4,6-tris(1-pyrrolidinyl)cyclohexadienylium-perchlorat 
• 123-75-1 pyrrolidine 
• 108-70-3 1,3,5-trichlorobenzene 
• 122408-35-9 1-Iod-2,4,6-tris(1-pyrrolidinyl)cyclohexadienylium-iodid 

Downstream Products

• 115827-94-6 ethyl 2,4,6-tripyrrolidin-1-ylbenzyl ether 
• 33949-06-3 2,4,6-Tripyrrolidino-2'-cyano-4'-nitrobiphenyl 
• 87370-87-4 2,4,6-Tripyrrolidino-2'-(methoxycarbonyl)-4'-nitrobiphenyl 
• 16857-92-4 3,5-(dipyrrolidine-1-yl)phenol 
• 122408-35-9 1-Iod-2,4,6-tris(1-pyrrolidinyl)cyclohexadienylium-iodid 
• 122408-40-6 1-oxo-2,4,6-tris(1-pyrrolidinyl)cyclohexadienylium perchlorate 
• 122408-37-1 1-Iod-2,4,6-tris(1-pyrrolidinyl)cyclohexadienylium-perchlorat 
• 122408-38-2 2,2',4,4',6,6'-Hexakis(1-pyrrolidinyl)-1,1'-bi(cyclohexadienyl)-diium-tetraiodid 
• 128244-29-1 1,3,5-tripyrrolidin-1-ylbenzene-d3 
• 29531-65-5 2,2',4,4',6,6'-hexapyrrolidin-1-yl-1,1'-bicyclohexadienylium diperchlorate 
• 70742-97-1 2-Chlor-1,3,5-tripyrrolidinobenzol 
• 137041-82-8 C₁₈H₂₅Cl₂N₃ 
• 137041-86-2 C₁₈H₂₄Cl₃N₃ 
• 103979-21-1 1-(3,5-Di-pyrrolidin-1-yl-cyclohexa-2,5-dienylidene)-pyrrolidinium 

Relevant academic research and scientific papers

Evidence for carbon-carbon meisenheimer-wheland complexes between superelectrophilic and supernucleophilic carbon reagents

(Chemical Equation Presented) Proposal accepted: NMR experiments have shown unequivocally that the previously only proposed zwitterionic carbon-carbon Meisenheimer-Wheland complexes are formed in the reaction of 4,6-dinitrobenzofuroxan (DNBF) with 1,3,5-tris(N,N-dialkylamino)benzenes. Increasing the temperature results in a rapid exchange between three homomeric forms of the complex (see scheme; NR2 = piperidyl, morpholinyl, pyrrolidinyl).

Quantification of the Lewis Basicities and Nucleophilicities of 1,3,5-Tris(dialkylamino)benzenes

Equilibrium constants for the formation of Wheland complexes from 1,3,5-tris(dialkylamino)benzenes and benzhydrylium ions (Ar2CH+) have been determined photometrically in dichloromethane solution at 20 °C. The Lewis basicity of the r

Nickel-catalysed sequential amination of aryl- and heteroaryl di- and trichlorides

Unsymmetrical 1,3-diaminobenzenes and diaminopyridines were efficiently prepared by reaction of 3-chloroanilines and chloroaminopyridines with amines via a nickel-catalysed amination. The Ni/2,2′-bipyridine catalyst is also effective for the sequential am

Aminobenzenes, 21. - Electron Transfer in the Reactions of Halogeno ?-complexes of 1,3,5-Tris(1-pyrrolidinyl)benzene with Nucleophiles

Iodo, bromo, chloro , and thiocyanato ?-complexes 4, accessible as crystalline compounds from 1,3,5-tris(1-pyrrolidinyl)benzene (1) with halogens and dirhodan, respectively, react with nucleophiles or bases under dehalogenation, deprotonation, dimerization, or H ?-complex formation.The product formation depends on the redox potentials of the ?-complexes ( acceptors) and the nucleophiles ( donors) , on the leaving tendency of the substituents on C-1 of the ?-complexes, and on the reaction time.The unexpected reactions are interpreted by an electron transfer from the nucleophile Y to the ?-complex A+ to give the radical A., a subsequent heterolytic dissociation to the 1,3,5-tris(1-pyrrolidinyl)benzene radical cation C+., and its follow-up reactions (addition of nucleophiles, dimerization, and H abstaction).The H ?-complex 6 results as the most stable final product after long reaction times because of its lowest acceptor properties and poor nucleofugal leaving tendency of a hydride ion.