295360-69-9

Basic information

• Product Name: N-((4-methoxyphenyl)(phenyl)methyl)-4-nitrobenzenesulfonamide
• Synonyms: N-((4-methoxyphenyl)(phenyl)methyl)-4-nitrobenzenesulfonamide
• CAS NO: 295360-69-9
• Molecular Weight: 398.439
• Mol File: 295360-69-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-((4-methoxyphenyl)(phenyl)methyl)-4-nitrobenzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-((4-methoxyphenyl)(phenyl)methyl)-4-nitrobenzenesulfonamide(295360-69-9)
• EPA Substance Registry System: N-((4-methoxyphenyl)(phenyl)methyl)-4-nitrobenzenesulfonamide(295360-69-9)

Safety Data

• Hazardous Substances Data: 295360-69-9(Hazardous Substances Data)

Upstream product

• 63160-16-7 4-nitro-N-(phenylmethylene)benzenesulfonamide 
• 5720-07-0 4-methoxyphenylboronic acid 
• 853955-69-8 [2-(hydroxymethyl)phenyl]dimethyl(phenyl)silane 
• 840529-62-6 N-p-nosyl-4-methoxy-phenylmethylimine 

Relevant articles and documents

A homogeneous, recyclable polymer support for rh(I)-catalyzed c-c bond formation

A robust and practical polymer-supported, homogeneous, recyclable biphephos rhodium(I) catalyst has been developed for C-C bond formation reactions. Control of polymer molecular weight allowed tuning of the polymer solubility such that the polymer-supported catalyst is soluble in nonpolar solvents and insoluble in polar solvents. Using the supported rhodium catalysts, addition of aryl and vinylboronic acids to the electrophiles such as enones, aldehydes, N-sulfonyl aldimines, and alkynes occurs smoothly to provide products in high yields. Additions of terminal alkynes to enones and industrially relevant hydroformylation reactions have also been successfully carried out. Studies show that the leaching of Rh from the polymer support is low and catalyst recycle can be achieved by simple precipitation and filtration.