29558-82-5

Upstream product

• 122-01-0 4-chloro-benzoyl chloride 
• 99-93-4 4-Hydroxyacetophenone 
• 104-88-1 4-chlorobenzaldehyde 

Downstream Products

• 79615-82-0 ω-bromo-4-(4-chlorobenzoyloxy)acetophenone 
• 79615-38-6 4-Chloro-benzoic acid 4-(2-amino-thiazol-4-yl)-phenyl ester; hydrobromide 
• 79040-25-8 2-amino-4-<4-(4-chlorobenzyloxy)phenyl>thiazole hydrobromide 
• 79040-37-2 2-acetamido-4-<4-(Chlorobenzyloxy)phenyl>thiazole 

Relevant academic research and scientific papers

Transesterification for synthesis of carboxylates using aldehydes as acyl donors via C-H and C-O bond activations

A new type of transesterification between aryl, heteroaryl, alkyl N-heteroarene-2-carboxylates and various aldehydes by C-H and C-O bond activations has been developed for the synthesis of versatile carboxylates. A possible mechanism containing oxidative addition of acyl-O bond in parent ester and radical cleavage of sp2 C-H bond in aldehyde is proposed.