2958-44-3Relevant academic research and scientific papers
Direct C–S Bond Functionalization of Benzyl Mercaptan
Choudhuri, Khokan,Mal, Prasenjit,Pramanik, Milan
, (2020)
Cleavage of a C–S bond of benzyl mercaptan led to formation of a new C–C bond during (Z)-selective alkenylation of nitriles using 1,10-phenanthroline as organocatalyst and tBuOK as a base. Furthermore, we have shown that the cascaded functionalization of benzylic C–S and aryl–halide bonds could be done in one pot. 1H NMR study and kinetic experiments also helped to establish the mechanism of the reaction.
CuCl-catalyzed regio- and stereoselective aminohalogenation of α,β-unsaturated nitriles
Han, Jian-Lin,Zhi, San-Jun,Wang, Le-Yong,Pan, Yi,Li, Guigen
, p. 1332 - 1337 (2008/09/17)
α,β-Unsat1urated nitriles were found to be suitable substrates for aminochlorination with N,N-dichloro-p-toluenesulfonamide (4-TsNCl 2) in the presence of CuCl as the catalyst (10 mol-%) and 4 A molecular sieves. The reaction is very convenient
