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Usage

Uses

Used in Chemical Synthesis:
2-Chlorobenzyl Mercaptan is used as a key intermediate in the synthesis of various organic compounds, particularly in the pharmaceutical and agrochemical industries. Its unique chemical structure allows for versatile reactions and functional group manipulations, making it a valuable building block for the development of new molecules with specific biological activities.
Used in Surface Chemistry:
2-Chlorobenzyl Mercaptan is used as a self-assembling monolayer (SAM) component for the formation of organized molecular films on solid surfaces, such as gold films. These monolayers are crucial in various applications, including the fabrication of sensors, microelectronic devices, and nanoscale structures. The chemisorption of 2-Chlorobenzyl Mercaptan on gold surfaces allows for the creation of stable and well-ordered monolayers, which can be further functionalized or used as templates for the assembly of more complex structures.
Used in Analytical Chemistry:
Due to its reactivity and affinity for gold surfaces, 2-Chlorobenzyl Mercaptan is employed in analytical chemistry for the detection and quantification of gold and other metal ions. It can be used as a selective reagent in colorimetric or spectroscopic assays, enabling the sensitive and specific detection of target analytes in various sample matrices.
Used in Material Science:
2-Chlorobenzyl Mercaptan can be utilized in the development of new materials with tailored properties, such as self-healing materials, stimuli-responsive polymers, and conductive polymers. Its ability to form stable monolayers and interact with metal surfaces makes it a promising candidate for the design of advanced materials with applications in electronics, sensors, and energy storage devices.

Upstream product

• 735278-03-2 bis(2-chlorobenzyl) sulfide 
• 611-19-8 1-chloro-2-(chloromethyl)benzene 
• 17356-08-0 thiourea 
• 3778-85-6 2-chlorophenylmethyl carbamimidothioate hydrochloride 
• 131887-60-0 [(2-Chloro-benzylsulfanyl)-dimethylamino-methylene]-dimethyl-ammonium; iodide 
• 2082-66-8 2-chlorobenzylthiocyanate 
• 13571-63-6 Carbamic acid 2-chloro-benzyl ester 

Downstream Products

• 5219-70-5 1,2-bis(2-chlorobenzyl)disulfane 
• 39885-69-3 5-methyl-oxazolidine-3-carbothioic acid S-(2-chloro-benzyl) ester 
• 27657-12-1 1-(2-Chloro-benzyldisulfanyl)-adamantane 
• 121041-48-3 6-(2'-chlorobenzylthio)pyridazin-3-amine 
• 75663-55-7 4-(2-fluorophenyl)-1,2,3,6-tetrahydro-1-methylpyridine 
• 72364-43-3 4-(2-Chloro-benzylsulfanyl)-4-(2-fluoro-phenyl)-1-methyl-piperidine 
• 75155-64-5 hexakis-(2-chlorobenzylthiomethyl)benzene 
• 89040-09-5 2-chlorobenzyl 2-hydroxyethyl monosulfide 
• 476362-80-8 5-(2-chloro-benzylsulfanyl)-3(9H-fluoren-9-ylmethoxycarbonylamino)-4-oxo-pentanoic acid tert-butyl ester 

Relevant academic research and scientific papers

PRODUCTION METHOD OF AROMATIC COMPOUND

PROBLEM TO BE SOLVED: To provide a BTBT ring (or DNTT ring)construction method in which a reaction proceeds under atmosphere and a low temperature (200°C or lower) without separately adding a substance to be a sulfur source as a raw material, and without using a raw material having corrosiveness, irritation, toxicity, and ignitability. SOLUTION: By using a specific thiol group-containing compound as a matrix raw material(starting compound), without adding a sulfur source substance, under atmosphere and low temperature (200°C or lower), a BTBT ring (or DNTT ring) may be obtained. SELECTED DRAWING: None COPYRIGHT: (C)2020,JPOandINPIT

Phosphorus Pentasulfide Mediated Conversion of Primary Carbamates into Thiols

In this paper, we report a method for the conversion of primary carbamates into thiols in the presence of phosphorus pentasulfide (P 2 S 5) in refluxing toluene. Presently, no method exists in the literature for conversion of carbamates into thiols and, to the best of our knowledge, it is the first report for this type of conversion. This method presents an indirect route for the conversion of alcohols into thiols via their carbamate derivatives that may be useful in the total synthesis of compounds containing a thiol functionality.

Phosphorus pentasulfide mediated conversion of organic thiocyanates to thiols

In this paper we report an efficient and mild procedure for the conversion of organic thiocyanates to thiols in the presence of phosphorus pentasulfide (P2S5) in refluxing toluene. The method avoids the use of expensive and hazardous transition metals and harsh reducing agents, as required by reported methods, and provides an attractive alternative to the existing methods for the conversion of organic thiocyanates to thiols.

Sulfur-containing imidazoles

Novel imidazole mercaptals of the formula STR1 wherein each m is independently zero or one; and R1 and R2 each are independently selected from (lower)alkyl, cycloalkyl, cycloalkyl(lower)alkyl, phenyl, phenyl(lower)alkyl, thienyl, thienyl(lower)alkyl, pyridyl and pyridyl(lower)alkyl, in which the phenyl and heterocyclic rings optionally may contain from 1 to 3 substituents, and acid addition salts thereof, are useful antimicrobial agents.

Dioxalane containing imidazole compounds, compositions and use

Compounds useful as antifungal, antibacterial and antiprotozoal agents are represented by the formula: STR1 wherein: Z is oxygen or sulfur; R1 is phenyl optionally substituted with one or more substituents selected from the group consisting of halo, lower alkyl of one to four carbon atoms, lower alkoxy of one to four carbon atoms and trifluoromethyl; R2 is phenyl or benzyl wherein the phenyl ring of R2 is optionally substituted by one or more substituents selected from the group consisting of halo, lower alkyl of one to four carbon atoms, lower alkoxy of one to four carbon atoms and trifluoromethyl; or by a phenyl optionally substituted by halo, lower alkyl of one to four carbon atoms, lower alkoxy of one to four carbon atoms or trifluoromethyl; and the antimicrobial acid addition salts thereof.