29587-01-7

Basic information

• Product Name: 5-[2,2-dimethyl-(4R)-1,3-dioxolan-4-yl]-2,2-dimethyl-(3aR,5R,6R,6aR)-perhydrofuro[2,3-d][1,3]dioxol-6-yl methyl ether
• CAS NO: 29587-01-7
• Molecular Weight: 274.314
• Mol File: 29587-01-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 5-[2,2-dimethyl-(4R)-1,3-dioxolan-4-yl]-2,2-dimethyl-(3aR,5R,6R,6aR)-perhydrofuro[2,3-d][1,3]dioxol-6-yl methyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: 5-[2,2-dimethyl-(4R)-1,3-dioxolan-4-yl]-2,2-dimethyl-(3aR,5R,6R,6aR)-perhydrofuro[2,3-d][1,3]dioxol-6-yl methyl ether(29587-01-7)
• EPA Substance Registry System: 5-[2,2-dimethyl-(4R)-1,3-dioxolan-4-yl]-2,2-dimethyl-(3aR,5R,6R,6aR)-perhydrofuro[2,3-d][1,3]dioxol-6-yl methyl ether(29587-01-7)

Safety Data

• Hazardous Substances Data: 29587-01-7(Hazardous Substances Data)

Upstream product

• 2595-05-3 Diacetone D-glucose 
• 74-88-4 methyl iodide 
• 582-52-5 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 2847-00-9 1,2:5,6-di-O-isopropylidene-α-D-hexofuran-3-ulose 
• 14686-89-6 (1,2:5,6)-di-O-isopropylidene-D-gulose 

Downstream Products

• 949586-03-2 C₂₆H₃₅O₅SiN₃ 
• 949586-02-1 6-O-tert-butyldiphenylsilyl-1,2-di-O-isopropylidene-3-O-methyl-α-D-allofuranose 
• 676342-57-7 6-O-tert-butyldiphenylsilyl-1,2-di-O-isopropylidene-3-O-methyl-β-L-talofuranose 
• 18968-51-9 1,2-O-isopropylidene-3-O-methyl-α-D-ribo-pentodialdo-1,4-furanose 
• 1391351-19-1 (R)-methyl 3-((3aR,5R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]-dioxol-5-yl)-3-((R)-2-methoxy-2-phenylacetamido)propanoate 
• 1391351-20-4 (R)-methyl 3-((3aR,5R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]-dioxol-5-yl)-3-((S)-2-methoxy-2-phenylacetamido)propanoate 
• 1391351-21-5 (S)-methyl 3-((3aR,5R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]-dioxol-5-yl)-3-((R)-2-methoxy-2-phenylacetamido)propanoate 
• 1391351-22-6 (S)-methyl 3-((3aR,5R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro[2,3-d][1,3]-dioxol-5-yl)-3-((S)-2-methoxy-2-phenylacetamido)propanoate 
• 1391351-13-5 methyl (3R)-3-benzylamino-3-[6-methoxy-2,2-dimethyl-(3aR,6R,6aR)-perhydrofuro[2,3-d][1,3]dioxol-5-yl]propanoate 
• 1391351-14-6 methyl (3S)-3-benzylamino-3-[6-methoxy-2,2-dimethyl-(3aR,6R,6aR)-perhydrofuro[2,3-d][1,3]dioxol-5-yl]propanoate 
• 1338971-63-3 C₁₇H₂₄O₅ 
• 3370-81-8 (3R,4R,5R,6R)-6-Hydroxymethyl-4-methoxy-tetrahydro-pyran-2,3,5-triol 

Relevant articles and documents

β-Oxygen effect in the Barton-McCombie deoxygenation reaction: Further experimental and theoretical findings

The chemistry of (S)-methyl xanthates derived from xylo- and ribo-furanose derivatives in the presence of the stannyl radical is investigated. Xanthate derived from β-xylo-furanose affords exclusively a deoxygenated product; whereas, under the same reacti

Synthesis of mycinose from 1,2:5,6-Di-O-isopropylidene-α-D- glucofuranose

A facile synthesis of mycinose from commercially available 1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose was developed. A selective and direct reductive debromination of α-hydroxy bromides in a simple NaBH4/EtOH/H2O system was found.

Ring-modified analogues and molecular dynamics studies to probe the requirements for fungicidal activities of malayamycin A and its N-nucleoside variants

(Chemical Equation Presented) The importance of functional group orientations and the integrity of the bicyclic perhydrofuran core of malayamycin A and two equally active N-nucleoside analogues as fungicides were investigated. Two analogues 10 and 11, representing a THP-truncated and a bicyclic aza-variant, were synthesized and found to be inactive. Molecular dynamics studies on malayamycin A and analogues were performed to highlight the importance of properly orientating the urea and methyl ether groups.