296238-69-2Relevant academic research and scientific papers
A new preparative method for the synthesis of diethyl 1-diazo-2,2,2- trifluoroethylphosphonate via an imino phosphonate
Karimova,Vorobyeva,Shchetnikov,Osipov
, p. 107 - 109 (2010)
A preparative method for the synthesis of diethyl 1-diazo-2,2,2- trifluoroethylphosphonate from trifluoroacetic anhydride and benzyl carbamate via diethyl 1-benzyloxycarbonylimino-2,2,2-trifluoroethylphosphonate is developed. Optimum conditions for the ch
α-CF3-substituted phosphorus containing analogs of α-amino acids. Novel six- and seven-membered α-amino phosphonates via ring closing metathesis with LnRu=C=C=CR2 precatalyst
Osipov, Sergey N.,Artyushin, Oleg I.,Kolomiets, Alexey F.,Bruneau, Christian,Dixneuf, Pierre H.
, p. 1031 - 1033 (2007/10/03)
α-CF3-substituted α-amino phosphonates with two alkene chains, 1,7- dienes and 1,8-dienes, were obtained by nucleophilic addition to highly electrophilic imines PG-N=C(CF3)P(O)(OR)2. They were treated with the ring closing
