296238-75-0Relevant academic research and scientific papers
Synthesis of fluorine-containing cyclic α-amino acid and α-amino phosphonate derivatives by alkene metathesis
Osipov, Sergey N.,Artyushin, Oleg I.,Kolomiets, Alexey F.,Bruneau, Christian,Picquet, Michel,Dixneuf, Pierre H.
, p. 3891 - 3897 (2007/10/03)
The electrophilic imino esters XF2CC(=NPG)CO2Me and imino phosphonates CF3CC(=NPG)P(O)(OR)2 (PG = SO2Ph, Cbz, Boc) were transformed by nucleophilic and then electrophilic additions into fluorine-conta
α-CF3-substituted phosphorus containing analogs of α-amino acids. Novel six- and seven-membered α-amino phosphonates via ring closing metathesis with LnRu=C=C=CR2 precatalyst
Osipov, Sergey N.,Artyushin, Oleg I.,Kolomiets, Alexey F.,Bruneau, Christian,Dixneuf, Pierre H.
, p. 1031 - 1033 (2007/10/03)
α-CF3-substituted α-amino phosphonates with two alkene chains, 1,7- dienes and 1,8-dienes, were obtained by nucleophilic addition to highly electrophilic imines PG-N=C(CF3)P(O)(OR)2. They were treated with the ring closing
