29648-80-4Relevant academic research and scientific papers
Competitive rearrangements of alkylacetoxycarbenes
Moss, Robert A.,Xue, Song,Ma, Wei,Ma, Huarong
, p. 4379 - 4382 (2007/10/03)
Absolute rate constants are determined for (1,2) acetyl, carbon, andhydride shifts in cyclobutylacetoxycarbene and isopropylacetoxycarbene; comparative reactivities are examined.
On the Mechanism of Graham's Reaction
Moss, Robert A.,Wlostowska, Joanna,Guo, Wenjeng,Fedorynski, Michal,Springer, James P.,Hirshfield, Jordan M.
, p. 5048 - 5050 (2007/10/02)
The oxidative cyclization of amidines to 3-chloro-3-substituted diazirines with aqueous sodium hypochlorite proceeds through N-chloro- and N,N'-dichloroamidines; the latter are isolable in certain cases.
