296783-77-2Relevant academic research and scientific papers
β-Dimethylphenylsilylethyl esters: A linker for solid-phase chemistry
Alonso, Concepción,Nantz, Michael H.,Kurth, Mark J.
, p. 5617 - 5622 (2007/10/03)
Preparation of a β-dimethylphenylsilylethyl (BMPSE) ester linker from 2% divinylbenzene-styrene copolymer by lithiation, chlorodimethylvinylsilane silylation, hydroboration/oxidation (giving 9), and O-acylation is reported. The resulting polymer-bound BMPSE esters were employed in a reaction sequence consisting of RCHO→RCH=NOH→isoxazoline/isoxazole (giving 12). (C) 2000 Elsevier Science Ltd.
