29736-81-0Relevant academic research and scientific papers
Radical Cation Cycloadditions Using Cleavable Redox Auxiliaries
Lin, Shishi,Lies, Shane D.,Gravatt, Christopher S.,Yoon, Tehshik P.
supporting information, p. 368 - 371 (2017/04/21)
The incorporation of an easily oxidized arylsulfide moiety facilitates the photocatalytic generation of alkene radical cations that undergo a variety of cycloaddition reactions with electron-rich reaction partners. The sulfide moiety can subsequently be reductively cleaved in a traceless fashion, affording products that are not otherwise directly accessible using photoredox catalysis. This approach constitutes a novel oxidative “redox auxiliary” strategy that offers a practical means to circumvent a fundamental thermodynamic limitation facing photoredox reactions.
SYNTHESIS OF SULFUR-CONTAINING HETEROCYCLES BY THERMOLYSIS OF α-ALKYLTHIO-N-AZIRIDINYLIMINES
Kim, Sunggak,Cho, Chang Mook
, p. 1971 - 1974 (2007/10/02)
Thermolysis of α-alkylthio substituted N-aziridinylimines in refluxing toluene gave various structurally different sulfur-containing heterocycles in high yields.
PREPARATION OF 1-ALKENYL PHENYL SULFIDES BY THE NICKEL(II)-COMPLEXES CATALYZED COUPLING REACTION OF 3-METHOXY-1-PHENYLTHIO-1-PROPENE WITH GRIGNARD REAGENTS
Sugimura, Hideyuki,Takei, Hisashi
, p. 1505 - 1508 (2007/10/02)
The reaction of on 3-methoxy-1-phenylthio-1-propene with aryl and primary alkyl Grignard reagents in the presence of nickel(II)-phosphine complex in benzene or toluene proceeded chemo- and regioselectively to give 1-alkenyl phenyl sulfides in high yields.
