55064-98-7

Upstream product

• 29736-81-0 phenyl(3-phenylprop-1-enyl)sulfane 
• 107-31-3 Methyl formate 
• 66080-30-6 pinacol 2-phenyl-1-(phenylthio)ethane-1-boronate 
• 134996-34-2 3-phenyl-2-phenylthio-2-propene-1-ol 
• 1504-58-1 3-Phenyl-2-propyn-1-ol 
• 108-98-5 thiophenol 
• 7205-91-6 phenylthiomethyl chloride 
• 13884-92-9 phenylthiomethyl triphenylphosphonium chloride 

Downstream Products

• 132331-46-5 2,2-Dimethyl-3-hydroxy-4-(phenylthio)-5-phenylpentanoic acid methyl ester 
• 132331-46-5 2,2-Dimethyl-3-hydroxy-4-(phenylthio)-5-phenylpentanoic acid methyl ester 

Relevant academic research and scientific papers

Atom-efficient gold(I)-chloride-catalyzed synthesis of α-sulfenylated carbonyl compounds from propargylic alcohols and aryl thiols: Substrate scope and experimental and theoretical mechanistic investigation

Gold(I)-chloride-catalyzed synthesis of α-sulfenylated carbonyl compounds from propargylic alcohols and aryl thiols showed a wide substrate scope with respect to both propargylic alcohols and aryl thiols. Primary and secondary aromatic propargylic alcohol

An aqueous and recyclable copper(i)-catalyzed route to α-sulfenylated carbonyl compounds from propargylic alcohols and aryl thiols

A highly efficient one-step copper(i)-catalyzed method for the synthesis of α-sulfenylated carbonyl compounds from propargylic alcohols and aryl thiols in aqueous media is described. A variety of α-sulfenylated carbonyl compounds can be synthesized in good to excellent yields. The catalyst has been successfully recycled up to 4 times without any loss of activity in an aqueous medium.

PREPARATION OF [ALPHA]-SULFENYLATED CARBONYL COMPOUNDS FROM PROPARGYLIC ALCOHOLS IN ONE STEP

The present relates to a method and a kit to produce an optically pure α-sulfenylated carbonyl compound comprising a primary or a secondary propargylic alcohol and an aryl thiol, a transition metal catalyst and a solvent.

A gold(I)-catalyzed route to α-sulfenylated carbonyl compounds from propargylic alcohols and aryl thiols

A one-step atom efficient gold(i)-catalyzed route to α-sulfenylated ketones and aldehydes from propargylic alcohols and aryl thiols is described.

A Novel Synthesis of 3,4-Dihydro-2H-1-benzothiopyrans. Acid-Catalyzed Intermolecular Cycloaddition of Acetylenic Alcohols with Arenethiols

Reaction of the acetylenic alcohols with arenethiols in the presence of p-toluenesulfonic acid (p-TsOH) gave 3,4-dihydro-2H-1-benzothiopyrans (thiochromans) in good to excellent yields, the reaction of which may involve intermolecular cycloaddition via ca