29740-66-7Relevant articles and documents
Unusual Kinetic Behavior in the Self-Reactions of Acyl Methyl Nitroxides
Griller, D.,Perkins M.J.
, p. 1354 - 1357 (1980)
The self-reactions of a series of acyl methyl nitroxides have been studied in solution.These reactions proceed by β-disproportionation, for which the measured rate constants lie in the range 101-103 M-1 s-1 at 2
Direct and Selective 3-Amidation of Indoles Using Electrophilic N-[(Benzenesulfonyl)oxy]amides
Ortiz, Gerardo X.,Hemric, Brett N.,Wang, Qiu
supporting information, p. 1314 - 1317 (2017/03/23)
Selective C-H amidation of 1H-indoles at the C3 position is reported as a direct entry to biologically important 3-aminoindoles. This transformation is achieved using novel N-[(benzenesulfonyl)oxy]amides as electrophilic nitrogen agents in the presence of ZnCl2. Interestingly, analogous reactions in the absence of ZnCl2 resulted in the formation of indole aminal products.
Process for the preparation of aldehydes and ketones
-
, (2008/06/13)
A process for the preparation of vinyl, alkynyl or aryl aldehydes or vinyl, alkynyl or aryl ketones includes reacting vinyl-, alkynyl- and aryl- and -methylene compounds with the aid of a mediator and an oxidant, wherein the mediator is selected from the group of the aliphatic, heterocyclic or aromatic NO or NOH containing compounds.
