29788-20-3Relevant articles and documents
UNUSUAL REACTION OF NITROSO COMPOUNDS WITH THE BIS(AMINOOXY)METHANE/DIBROMOISOCYANURATE SYSTEM
Smirnov, G. A.,Vasil'ev, A. M.,Luk'yanov, O. A.
, p. 2523 - 2524 (1991)
The reaction of nitroso compounds with bis(aminooxy)methane in the presence of dibromoisocyanurate gives the products of the formal replacement of the nitroso group by bromine.
Electrooxidative coupling of salts of nitro compounds with halide, nitrite, cyanide, and phenylsulfinate anions
Ilovaisky,Merkulova,Ogibin,Nikishin
, p. 1585 - 1592 (2007/10/03)
Electrolysis of salts of primary and secondary nitro compounds (nitroethane, 1- and 2-nitropropanes, nitrocyclohexane, and nitrocycloheptane) in the presence of excess halide, nitrite, cyanide, and phenylsulfinate anions under undivided and divided amperostatic electrolysis conditions in a two-phase medium (CH2Cl2/H2O) produces geminal nitrohalides (35-85% yields), dinitro compounds (15-51%), nitronitriles (6-27%), and nitrosulfones (50-70%). The salts of secondary nitro compounds form the products of oxidative coupling with halide and phenylsulfinate anions under the undivided electrolysis conditions. In all other cases, divided electrolysis is required.
Transformations of Cyclohexanone Oxime into gem-Dinitrocyclohexane
Moiseev,Nafikov,Makarova
, p. 607 - 608 (2007/10/03)
In reaction of cyclohexanone oxime with various electrophilic agents, the highest yields of gem-dinitrocyclohexane were obtained with N2O5 and O3 as oxidants and HNO3 in (CH3CO)2O as a nitrating agent.