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CAS

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2988-80-9

(1S,5R,6S)-6-Methoxy-bicyclo[3.1.0]hexane is a complex organic compound with a unique bicyclic structure. It consists of a six-membered ring with a methyl group at position 1, a hydroxyl group at position 5, and a methoxy group at position 6. The compound is characterized by its stereochemistry, with the 1S, 5R, and 6S configurations indicating the specific arrangement of atoms in three-dimensional space. This molecule is of interest in organic chemistry due to its potential applications in the synthesis of various pharmaceuticals and natural products, as well as its role as a chiral building block in asymmetric synthesis. The compound's properties, such as its reactivity and stability, are influenced by its stereochemistry, making it a valuable target for study in the field of stereoselective synthesis.

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  • 2988-80-9 Structure

  • Basic information

    1. Product Name: (1S,5R,6S)-6-Methoxy-bicyclo[3.1.0]hexane
    2. Synonyms:
    3. CAS NO:2988-80-9
    4. Molecular Formula:
    5. Molecular Weight: 112.172
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 2988-80-9.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (1S,5R,6S)-6-Methoxy-bicyclo[3.1.0]hexane(CAS DataBase Reference)
    10. NIST Chemistry Reference: (1S,5R,6S)-6-Methoxy-bicyclo[3.1.0]hexane(2988-80-9)
    11. EPA Substance Registry System: (1S,5R,6S)-6-Methoxy-bicyclo[3.1.0]hexane(2988-80-9)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 2988-80-9(Hazardous Substances Data)

2988-80-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 2988-80-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,9,8 and 8 respectively; the second part has 2 digits, 8 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 2988-80:
(6*2)+(5*9)+(4*8)+(3*8)+(2*8)+(1*0)=129
129 % 10 = 9
So 2988-80-9 is a valid CAS Registry Number.

2988-80-9Downstream Products

2988-80-9Relevant articles and documents

Deamination Reactions, 51. - Decomposition of Bicyclohexane-exo-6-diazonium Ions

Kirmse, Wolfgang,Hellwig, Georg

, p. 389 - 392 (2007/10/02)

The nitrous acid deamination of the amine 13, the copper(II)-induced cleavage of the nitrosourea 19, and the thermolysis of the nitrosoamide 20 were used to generate the diazonium ion 7.In contrast to previous work, performed in the presence of base, the neutral to weakly acidic conditions of the present study afforded substantial fractions (30-40percent) of bicyclohex-exo-6-yl products (15).Small quantities of bicyclohex-endo-6-yl (14), bicyclohex-2-yl (25, 26) and 3-cyclohexen-1-yl (27) derivatives were also detected, the latter arising by a 1,3-hydride shift.These results, unprecedented with higher homologs of 7, suggest a largely "classical" bicyclohex-6-yl cation (21) as the initially formed intermediate.Capture of 21 is thought to compete with disrotatory transformation to the cyclohexenyl cation 12. - Keywords: Bicyclohex-6-yl derivatives/ Diazonium ions/ Electrocyclic reactions/ Nucleophilic displacement

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