29943-11-1

Basic information

• Product Name: Cyclohexanone, 2-(2-oxobutyl)-
• CAS NO: 29943-11-1
• Molecular Formula: C10H16O2
• Molecular Weight: 168.236
• Mol File: 29943-11-1.mol

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2-(2-oxobutyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2-(2-oxobutyl)-(29943-11-1)
• EPA Substance Registry System: Cyclohexanone, 2-(2-oxobutyl)-(29943-11-1)

Safety Data

• Hazardous Substances Data: 29943-11-1(Hazardous Substances Data)

Upstream product

• 1125-99-1 1-(1-Cyclohexen-1-yl)pyrrolidine 
• 816-40-0 1-Bromo-2-butanone 
• 2783-12-2 2-nitrobutene 
• 108-94-1 cyclohexanone 
• 54166-48-2 2-(but-2-yn-1-yl)cyclohexan-1-one 
• 67722-24-1 3-bromo-2-methoxybut-1-ene 
• 10468-40-3 cyclohexanone N-cyclohexylimine 
• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 

Relevant articles and documents

One-Pot Synthesis of 1,4-Diketones from Nitroalkenes and Ketones

A convenient one-pot synthesis of 1,4-diketones was achieved by the conjugate addition of lithium enolates of ketones to nitroalkenes, followed by in situ hydrolysis of the resulting lithium salts of aci-nitro compounds with aqueous hydrochloric acid in tetrahydrofuran.

REGIOSELECTIVE HYDRATION OF ALKYNONES BY PALLADIUM CATALYSIS

Diketones are regioselectively prepared from alkynyl ketones under mild conditions by palladium catalysis; 5-heptyn-2-one and 2-(2-nonynyl)cyclohexanone give 1,4-diketones whereas 2-(2-heptynyl)cyclopentanone and 5,6-didehydroprostaglandin E2 methyl ester afford 1,5-diketones.