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(+/-)-1-(Diphenylphosphino)-2-(methylphenylphosphino)ethane, also known as dppe, is a bidentate ligand that is widely used in coordination chemistry. It is composed of two phosphine groups connected by a two-carbon bridge, forming a white solid at room temperature. Dppe is soluble in organic solvents such as dichloromethane and tetrahydrofuran. (+/-)-1-(Diphenylphosphino)-2-(methylphenylphosphino)ethane is known for its ability to coordinate with a wide range of metal ions, making it a versatile and important compound in inorganic and organometallic chemistry.

29955-01-9

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29955-01-9 Usage

Uses

Used in Coordination Compounds and Organometallic Complexes:
Dppe is used as a chelating ligand in the synthesis of coordination compounds and organometallic complexes. It helps stabilize metal ions, which is crucial for the formation and properties of these compounds.
Used in Catalysis:
In the field of catalysis, dppe plays a significant role, particularly in palladium-catalyzed coupling reactions. Its ability to coordinate with metal ions makes it an effective ligand in these catalytic processes, enhancing the efficiency and selectivity of the reactions.
Used in Inorganic and Organometallic Chemistry:
Dppe is a key compound in inorganic and organometallic chemistry due to its versatility in coordinating with various metal ions. This property allows it to be employed in a wide range of applications, from the synthesis of new compounds to the development of catalytic processes.

Check Digit Verification of cas no

The CAS Registry Mumber 29955-01-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 2,9,9,5 and 5 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 29955-01:
(7*2)+(6*9)+(5*9)+(4*5)+(3*5)+(2*0)+(1*1)=149
149 % 10 = 9
So 29955-01-9 is a valid CAS Registry Number.

29955-01-9Relevant academic research and scientific papers

Optically Active Asymmetric Bidentate Ligands. Crystal and Molecular Structure of -(-)589-naphthyl-C2,N>-palladium(II) Hexafluorop

Leitch, Jeffrey,Salem, Geoffrey,Hockless, David C. R.

, p. 649 - 656 (2007/10/02)

Asymmetric bidentate (+/-)-1-(diphenylphosphino)-2-(methylphenylphosphino)ethane has been resolved by the separation by fractional crystallisation of internally diastereomeric palladium(II) complexes containing the racemic ligand and orthometallated (R)-d

CLEAVAGE OF PHOSPHOROUS-CARBON BONDS WITH SODIUM/NAPHTHALENE. FACILE PREPARATION OF UNSYMMETRICAL DIPHOSPHINES

Chou, Ta-Shue,Tsao, Chung-Huang,Hung, Su Chun

, p. 53 - 58 (2007/10/02)

Sodium/naphthalene was found to be a homogeneous, mild and selective reagent for the reductive cleavage of aryl-phosphorous bonds.Such cleavage reactions are very useful in the convenient synthesis of unsymmetrical diphosphines from commercially available and air-stable diphosphines.

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