29972-16-5Relevant academic research and scientific papers
The crystal structure of 3-butenyltriphenylstannane. Crystal disorder and thermodynamic properties
Ganis, Paolo,Valle, Giovanni,Marton, Daniele,Tagliavini, Giuseppe
, p. 119 - 121 (1997)
The tin derivative 3-butenyltriphenylstannane [Ph3Sn-CH2-CH2-CH=CH2] (A) has been prepared; the crystal and molecular structure has been determined by X-ray analysis. The compound crystallizes in the tetragonal space group P421c with a = b = 11.860(3), c = 6.839(2) A, Z = 2. Refinement converged to the final R index 0.044. The crystal and physical data are compared with those of tetraphenyltin (B); the relevant differences are explained in terms of structural disorder.
Sulphur-substituted Organotin Compounds. Part 8. Preparation and Reactions of 3-(p-Tolylthio)propyl- and 4-(p-Tolylthio)butyl-triphenyltin. Interactions with Tetracyanoethylene
Wardell, James L.,Wigzell, John McM.
, p. 2321 - 2326 (2007/10/02)
The reactions of SnPh3 (n= 3 or 4) with mercury(II) chloride, bromine and iodine lead to phenyl-tin bond cleavage.In contrast, reactions with methyl iodide provide SnPh3 and MeSC6H4Me-p.Charge-transfer adducts are formed between SnPh3 (n= 1-4) and tetracyanoethylene or p-bromoanil.The values of λmax. of the complexes indicate similar donor character for SnPh3 (n= 2,3, or 4); however, the compound SnPh3(CH2SC6H4Me-p) is a stronger donor.
New Reagents, XX. (Triphenylstannyl)methyllithium and Analogous Trialkylstannyl Compounds, Synthesis and Reactions
Kauffmann, Thomas,Kriegesmann, Reinhard,Altepeter, Bruno,Steinseifer, Fritz
, p. 1810 - 1817 (2007/10/02)
(Triphenylstannyl)methyllithium (1a) and analogous trialkylstannyl compounds (1b, c) were synthesized by halogen-lithium exchange reactions from 3a - c.As shown by high yields, stannyl groups are capable of stabilizing a carbanionic centre. 1a reacts with aldehydes and ketones to give β-hydroxystannanes 5 which tend to form olefins.
