33550-56-0

Basic information

• Product Name: Stannane, (iodomethyl)triphenyl-
• CAS NO: 33550-56-0
• Molecular Formula: C19H17ISn
• Molecular Weight: 490.958
• Mol File: 33550-56-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Stannane, (iodomethyl)triphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Stannane, (iodomethyl)triphenyl-(33550-56-0)
• EPA Substance Registry System: Stannane, (iodomethyl)triphenyl-(33550-56-0)

Safety Data

• Hazardous Substances Data: 33550-56-0(Hazardous Substances Data)

Upstream product

• 75-11-6 diiodomethane 
• 639-58-7 triphenyltin chloride 
• 4167-90-2 lithium triphenylstannide 
• 42393-74-8 (C₆H₅)3SnCH₂CH₂N(C₆H₅)2 
• 42393-72-6 (C₆H₅)3SnCH₂CH₂N(CH₃)C₆H₅ 
• 7790-28-5 sodium periodate 
• 75-03-6 ethyl iodide 
• 4109-94-8 (iodomethyl)zinc iodide 

Downstream Products

• 821-55-6 2-Nonanone 
• 24066-87-3 non-1-en-2-ylbenzene 
• 965-16-2 1,2-bis(benzo[d]thiazol-2-yl)ethane 
• 1064-10-4 hexaphenylditin 
• 2591-30-2 1,2-bis(triphenylstannyl)ethane 
• 71828-34-7 1,1-bis(triphenylstannyl)methane 
• 140847-27-4 (benzothiazolyl-2-thiomethyl)diphenyltin iodide 
• 140847-29-6 (benzoxazolyl-2-thiomethyl)diphenyltin iodide 
• 140847-28-5 (benzothiazolyl-2-thiomethyl)diphenyltin bromide 
• 140847-31-0 (pyrimidinyl-2-thiomethyl)diphenyltin chloride 
• 181044-05-3 μ-(N,N'-bis[trans-5-(methoxymethyl)-2-phenyl-1,3-dioxan-5-yl]ethanediamide(2-))bis(triphenyltin) 
• 192325-03-4 [(R)-menthyl]2PCH₂SnPh₃ 
• 235422-44-3 Mes₂PCH₂SnPh₃ 
• 82758-95-0 (C₆H₅)3SnCH₂SeC₆H₅ 

Relevant articles and documents

Homologation of halostannanes with carbenoids: a convenient and straightforward one-step access to α-functionalized organotin reagents

A direct, single synthetic homologative transformation of halostannanes into mono- or di-substituted methyl analogues is documented. Critical for the success of the operation is the excellent nucleophilicity of carbenoid-like methyllithium reagents (LiCHXY, X, Y = halogen, OR, and CN): by simply individuating the reagents' substitution pattern, the desired functionalized fragment is delivered to the electrophile. The wide scope of the protocol is evidenced also in the case of analogous halogermanium compounds. The tandem homologation-quenching with nucleophiles and the use of α-chloroallyllithium is also discussed.