29972-74-5

Basic information

• Product Name: (4-dimethylamino-phenyl)-phosphonous acid dichloride
• Synonyms: (4-dimethylamino-phenyl)-phosphonous acid dichloride
• CAS NO: 29972-74-5
• Molecular Weight: 222.054
• Mol File: 29972-74-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (4-dimethylamino-phenyl)-phosphonous acid dichloride(CAS DataBase Reference)
• NIST Chemistry Reference: (4-dimethylamino-phenyl)-phosphonous acid dichloride(29972-74-5)
• EPA Substance Registry System: (4-dimethylamino-phenyl)-phosphonous acid dichloride(29972-74-5)

Safety Data

• Hazardous Substances Data: 29972-74-5(Hazardous Substances Data)

Upstream product

• 121-69-7 N,N-dimethyl-aniline 
• 7719-12-2 phosphorus trichloride 
• 93296-10-7 (4-(dimethylamino)phenyl)zinc(II) chloride 
• 586-77-6 4-bromo-N,N-dimethylaniline 
• 4219-76-5 4,4'-mercuriobis(N,N-dimethylaniline) 

Downstream Products

• 1104-21-8 tris(p-dimethylaminophenyl)phosphine 
• 125787-84-0 {4-[Bis-(2-morpholin-4-yl-cyclopent-1-enyl)-phosphanyl]-phenyl}-dimethyl-amine 
• 131373-38-1 <(1,3,3-trimethyl-2-indolinylidene)methyl>phosphinous chloride 
• 131373-32-5 bis<(1,3,3-trimethyl-2-indolinylidene)methyl>phosphine 
• 75018-40-5 4-(N,N-Dimethylanilino)-bis-(trimethylsilyl)phosphan 
• 7647-01-0 hydrogenchloride 
• 86119-84-8 phosphoric acid 
• 20683-98-1 4-N,N-dimethylaminophenylphosphinic acid 
• 121-69-7 N,N-dimethyl-aniline 
• 13406-23-0 4-Trifluormethyl-N--anilin 
• 14474-87-4 4-Nitro-N--anilin 
• 14655-52-8 Allyl-<4-dimethylamino-phenyl>-phosphinsaeure-allylester 
• 38343-23-6 {4-[Bis-(4-nitro-phenylethynyl)-phosphinoyl]-phenyl}-dimethyl-amine 
• 2067-89-2 Diphenyl-benzyl-<4-dimethylaminophenyl>-phosphoniumbromid 

Relevant articles and documents

Reactive intermediates: A transient electrophilic phosphinidene caught in the act

Trapped! Transient electrophilic phosphinidenes [R-P=W(CO)5] have emerged as versatile intermediates that are highly valuable in the synthesis of a plethora of organophosphorus compounds, nevertheless their existence has never been unequivocall

Metal control of non-polar binding shape selectivity

Ligand 1 forms a hydrophobic cavity upon binding to metals, the shape of which depends on the metal. A reversal in binding preference for naphthalene or biphenyl groups is found when the metal is changed from zinc to copper, with a selectivity change of 260 fold.

The kinetics and mechanism of the reaction of tricoordinate phosphorus compounds with sulfenate esters

The kinetics and mechanism of the reaction of tricoordinate phosphorus compounds, ArnP(OCH2CF3)3-n with arylsulfenate esters, ArSOCH2CF3, are reported. Product analysis, kinetic order, activation parameters, Hammett data and solvent effects are the criteria used to elucidate the two step mechanism involving arylthiophosphoranes as intermediates.