300568-63-2Relevant academic research and scientific papers
Facile one-pot synthesis of cyclic N-sulfonylamidines from lactam and sulfonamide
Mulati, Ayinigeer,Wusiman, Abudureheman
, p. 2163 - 2171 (2015)
A simple method has been developed for one-pot synthesis of five-, six- And seven-membered cyclic N-sulfonylamidines from lactams and sulfonamides under mild conditions. The method involves a Vilsmeier like reaction promoted by phosphoryl chloride. Detail
Dirhodium(II) complexes of 2-(sulfonylimino)pyrrolidine: Synthesis and application in catalytic benzylic oxidation
Wusiman, Abudureheman,Tusun, Xiarepati,Lu, Chong-Dao
supporting information; experimental part, p. 3088 - 3092 (2012/06/30)
A new class of dirhodium(II) tetraamidinates derived from 2-(sulfonylimino)pyrrolidines has been prepared through ligand substitution by using dirhodium(II) acetate, in which (3,1) geometric isomers are formed predominantly. Among these complexes, (3,1)-Rh2(Msip)4, exhibits good catalytic performance in benzylic oxidation. In the presence of (3,1)-Rh2(Msip)4 a variety of benzylic derivatives, including strongly electron-deficient arylalkanes such as 1-ethyl-4- nitrobenzene, are readily oxidized in water by the inexpensive oxidant T-HYDRO (70 wt.-% aqueous tert-butyl hydroperoxide). Copyright
