3007-71-4

Basic information

• Product Name: N-octylaniline
• Synonyms: 1-Octanamine, N-phenyl-; Aniline, N-octyl-; benzenamine, N-octyl-; N-n-octylaniline; N-Octylaniline; Octylamine, N-phenyl-; Phenyloctylamine
• CAS NO: 3007-71-4
• Molecular Formula: C₁₄H₂₃N
• Molecular Weight: 205.3391
• Mol File: 3007-71-4.mol
• Article Data: 129

Chemical Properties

• Boiling Point: 310.2°C at 760 mmHg
• Flash Point: 141.9°C
• Density: 0.914g/cm³
• Vapor Pressure: 0.000609mmHg at 25°C
• Refractive Index: 1.52
• CAS DataBase Reference: N-octylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-octylaniline(3007-71-4)
• EPA Substance Registry System: N-octylaniline(3007-71-4)

Safety Data

• Hazardous Substances Data: 3007-71-4(Hazardous Substances Data)

Usage

General Description

N-octylaniline, also known as octylphenylamine, is an organic compound with the chemical formula C14H23N. It is a colorless to pale yellow liquid with a faint amine-like odor. N-octylaniline is commonly used as an intermediate in the production of dyes, antioxidants, and pharmaceuticals. It is also utilized as an oil additive to improve oxidation stability and corrosion inhibition in lubricants. Additionally, N-octylaniline is used as a stabilizer in the formulation of polyurethane foam. However, exposure to N-octylaniline has been associated with potential health hazards, including skin and eye irritation, and it should be handled and used with caution.

Upstream product

• 111-87-5 octanol 
• 142-04-1 aniline hydrochloride 
• 111-83-1 1-bromo-octane 
• 103-70-8 Formanilid 
• 7438-05-3 1-azidooctane 
• 71-43-2 benzene 
• 14866-33-2 tetraoctyl ammonium bromide 
• 62-53-3 aniline 
• 538-51-2 benzylidene phenylamine 
• 108-86-1 bromobenzene 
• 111-86-4 n-Octylamine 
• 108-94-1 cyclohexanone 
• 108-93-0 cyclohexanol 
• 124-07-2 Octanoic acid 

Downstream Products

• 114201-82-0 N-octyl-toluene-4-sulfonanilide 
• 124-13-0 Octanal 
• 16245-79-7 4-octylaniline 
• 62-53-3 aniline 
• 1311478-33-7 C₃₆H₅₈N₄O₂ 
• 251476-87-6 2'-hydroxy-3,3-bis-trifluoromethyl-[1,1':3'1]terphenyl-5'-carboxylic acid (8-phenyl-octyl)-amide 
• 251477-39-1 N-(8-phenyl-octyl)-3,5-bis(m-trifluoromethylphenyl)-4-(2-hydroxyethoxy)-benzamide 
• 1167-42-6 toluene-4-sulfonic acid-(4-octyl-anilide) 
• 213190-22-8 Octyl-phenyl-dithiocarbamic acid methyl ester 
• 83715-95-1 10-Octyl-3-phenyl-10H-pyrimido[4,5-b]quinoline-2,4-dione 
• 2567-54-6 chloro-acetic acid-(N-octyl-anilide) 
• 55239-84-4 C₁₅H₂₂ClNO 

Relevant articles and documents

Synthesis of an Fe-Pd bimetallic catalyst for: N -alkylation of amines with alcohols via a hydrogen auto-transfer methodology

Hydrogen auto-transfer (HAT) or borrowing hydrogen (BH) methodology which combines dehydrogenation, intermediate reaction and hydrogenation, is recognized as an excellent strategy for one-pot synthesis from an economic and environmental point of view. Although much effort has been made on the development of catalysts for HAT reactions, harsh conditions, external base or large amounts of noble metals are still required in most reported catalysis systems, and thus the exploration of a highly efficient and recyclable heterogeneous catalyst remains meaningful. In this work, a novel bimetallic catalyst, Fe10Pd1/NC500 derived from bimetallic MOF NH2-MIL-101(Fe10Pd1), has been prepared, and the catalyst exhibits superior catalytic performance for the N-alkylation of amines with alcohols via a hydrogen auto-transfer methodology. High yields of the desired products were achieved at 120 °C with an alcohol/amine molar ratio of 2?:?1 and required no external additive or solvent. A distinct enhancement in catalytic performance is observed when compared with monometallic catalysts, which can be ascribed to the "synergistic effects"inside the bimetallic alloys. The N-doped carbon support has been revealed to provide the necessary basicity which avoids the requirement of an external base. Moreover, a wide substrate range and remarkable reusability have been shown by Fe10Pd1/NC500, and this work highlights new possibilities for bimetallic catalysts applied in sustainable chemistry.

Enhanced Hydride Donation Achieved Molybdenum Catalyzed Direct N-Alkylation of Anilines or Nitroarenes with Alcohols: From Computational Design to Experiment

An example of homogeneous Mo-catalyzed direct N-alkylation of anilines or nitroarenes with alcohols is presented. The DFT aimed design suggested the easily accessible bis-NHC-Mo(0) complex features a strong hydride-donating ability, achieving effective N-alkylation of anilines or challenging nitroarenes with alcohols. The enhanced hydride-donating strategy should be useful in designing highly active systems for borrowing hydrogen transformations.

Switchable Imine and Amine Synthesis Catalyzed by a Well-Defined Cobalt Complex

Switchable imine and amine synthesis catalyzed by a tripodal ligand-supported well-defined cobalt complex is presented herein. A large variety of primary alcohols and amines were selectively converted to imines or amines in good to excellent yields. It is discovered that the base plays a crucial role on the selectivity. A catalytic amount of base leads to the imine formation, while an excess loading of base results in the amine product. This strategy on product selectivity also strongly depends on the organometallic catalysts in use. We expect that the present study could provide useful insights toward selective organic synthesis and catalyst design.