302800-57-3

Basic information

• Product Name: methyl-2,3,5-tri-O-benzyl-D-lyxofuranoside
• Synonyms: methyl-2,3,5-tri-O-benzyl-D-lyxofuranoside
• CAS NO: 302800-57-3
• Molecular Weight: 434.532
• Mol File: 302800-57-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl-2,3,5-tri-O-benzyl-D-lyxofuranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl-2,3,5-tri-O-benzyl-D-lyxofuranoside(302800-57-3)
• EPA Substance Registry System: methyl-2,3,5-tri-O-benzyl-D-lyxofuranoside(302800-57-3)

Safety Data

• Hazardous Substances Data: 302800-57-3(Hazardous Substances Data)

Upstream product

• 1824-96-0 Methyl α-lyxofuranoside 
• 100-39-0 benzyl bromide 
• 87-72-9 D-lyxose 

Downstream Products

• 1198761-24-8 2,3,5-tri-O-benzyl-D-lyxose diethyl dithioacetal 
• 122565-72-4 2,3,5-tri-O-benzyl-D-lyxitol 
• 14233-60-4 1,3,4-tri-O-benzyl-D-erythro-pentulofuranose 
• 1392126-62-3 (-)-(2R,3R,4R,5S)-5-(6-Amino-9H-purin-9-yl)-1,3,4-tris(benzyloxy)-5-((trimethylsilyl)oxy)pentan-2-yl methanesulfonate 
• 1392126-58-7 (-)-(2R,3R,4R,5R)-1,3,4-tris(benzyloxy)-5-(2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)-5-((trimethylsilyl)oxy)pentan-2-yl methanesulfonate 
• 1392126-57-6 (-)-(2R,3R,4R,5S)-1,3,4-tris(benzyloxy)-5-(2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)-5-((trimethylsilyl)oxy)pentan-2-yl methanesulfonate 
• 158226-97-2 (-)-(2R,3S,4R)-1,3,4-tris(benzyloxy)-5,5-bis(ethylthio)pentan-2-ol 
• 302800-86-8 methyl 8-O-(3,4,6-tri-O-benzyl-1,2-dideoxy-D-lyxo-hex-1-enyl)-6,7,9-trideoxy-α-D-gluco-nona-8-enopyranoside 
• 302800-84-6 3,4,6-tri-O-benzyl-1,2-dideoxy-α-D-lyxo-hex-1-enyl (methyl 2,3,4-tri-O-benzyl-6,7-dideoxy-α-D-gluco-octopyranosid)uronate 
• 302800-90-4 methyl 8-O-(3,4,6-tri-O-benzyl-1,2-dideoxy-D-lyxo-hex-1-enyl)-6,7,9-trideoxy-1,2:3,4-di-O-isopropylidene-α-D-galacto-nona-8-enopyranose 
• 302800-88-0 3,4,6-tri-O-benzyl-1,2-dideoxy-D-lyxo-hex-1-enyl (6,7-dideoxy-1,2:3,4-di-O-isopropylidene-α-D-galacto-octopyranosid)uronate 
• 302800-64-2 3,4,6-tri-O-benzyl-1,2-dideoxy-D-lyxo-hex-1-enitol 
• 16838-89-4 2,3,5-tri-O-benzyl-D-lyxofuranoside 

Relevant articles and documents

An olefin metathesis route for the preparation of (1 → 6)-linked C-disaccharide glycals. A convergent and flexible approach to C-saccharide synthesis

A convergent route to a variety of C-1-disaccharide glycals based on the olefin metathesis reaction of enol ethers and alkenes is described. The DCC-mediated coupling reaction of a variety of pentose enitols (1a-c) with a number of C-5- and C-6-monosaccharide carboxylic acids (2a-e) gave the corresponding esters 3a-1 in good yield. Methylenation of these compounds was followed by ring-closing metathesis, mediated by the Schrock molybdenum catalyst 8 in warm toluene, to provide the target C-disaccharide glycals 5a-1. The formed enol ether double bond in 5a was then transformed, via standard manipulations, into a variety of C-disaccharide derivatives 21-25.