303082-41-9

Upstream product

• 28920-43-6 (fluorenylmethoxy)carbonyl chloride 
• 175980-93-5 (2S,4aR,6S,7R,8R,8aR)-6-[Dimethyl-(1,1,2-trimethyl-propyl)-silanyloxy]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 

Downstream Products

• 303082-43-1 O-(2-O-benzoyl-4,6-O-benzylidene-3-O-(9-fluorenylmethoxycarbonyl)-α-D-galactopyranosyl) trichloroacetimidate 
• 303082-42-0 thexyldimethylsilyl 2-O-benzoyl-4,6-O-benzylidene-3-O-(9-fluorenylmethoxycarbonyl)-β-D-galactopyranoside 

Relevant academic research and scientific papers

Solid phase syntheses of oligomannosides and of a lactosamine containing milk trisaccharide using a benzoate linker

Galactose and mannose building blocks 9 and 12 were designed for the solid phase synthesis of oligosaccharides (SPOS). Both compounds were employed after condensation with benzoic acid function containing resin 10 in SPOS of human milk trisaccharide 1 and

O-Glycosyl trichloroacetimidates bearing Fmoc as temporary hydroxy protecting group: a new access to solid-phase oligosaccharide synthesis.

Different O-glycosyl trichloroacetimidates bearing base sensitive Fmoc protected hydroxy groups were efficiently prepared with CCl(3)CN using a catalytic amount of sodium hydride. The resulting glycosyl donors were engaged in glycosylation reactions both