303154-49-6Relevant academic research and scientific papers
Asymmetric Diels-Alder reaction between acrylates and cyclopentadiene in the presence of chiral catalysts
Mamedov
, p. 1621 - 1625 (2006)
Asymmetric Diels-Alder reaction between cyclopentadiene and alkyl and cycloalkyl acrylates in the presence of new chiral catalysts, BBr 3?MentOEt, AlCl2OMent, BBr2OMent, and BBr(OMent)2, was studied. Optically active bicyclo[2.2.1]hept-2-ene- 5-carboxylates were synthesized. The influence of the reaction conditions on the total and optical yields and on the stereoselectivity of the adducts synthesized was examined. Nauka/Interperiodica 2006.
Occurence of New Bifunctional Esters in Roman Camomile Oil (Anthemis nobilis L.)
Klimes, Ivan,Lamparsky, Dietmar,Scholz, Ernst
, p. 2338 - 2349 (2007/10/02)
Some novel aliphatic esters of the unusual 3-hydroxy-2-methylidenebutyric acid have been found in the commercially available essential oil.Additionally, esters of (Z)-2-methyl-2-butenoic acid of structurally similar diols or other bifunctional alcohols have also been identified.Spectral data as well as a synthetic approach to the new esters of 3-hydroxy-2-methylidenebutyric acid are given.
