303155-16-0Relevant academic research and scientific papers
Fragmentation of tertiary cyclopropanol compounds catalyzed by vanadyl acetylacetonate
Kirihara, Masayuki,Kakuda, Hiroko,Ichinose, Motohiro,Ochiai, Yuta,Takizawa, Shinobu,Mokuya, Asuka,Okubo, Kumiko,Hatano, Akihiko,Shiro, Motoo
, p. 4831 - 4839 (2007/10/03)
Tertiary cyclopropanol compounds react with a catalytic amount of vanadyl acetylacetonate in the presence of oxygen affording β-hydroxyketones and β-diketones. For 3-substituted-bicyclo[4.1.0]alkanols, peroxides are obtained, as are the β-hydroxyketones. Conversely, 2- ethoxycarbonylcyclopropyl silyl ethers produce ethyl γ-oxocarboxylate derivatives given the same reaction conditions.
Facile synthesis of oxatricyclic systems with various ring sizes and substituents
Muthusamy, Sengodagounder,Arulananda Babu, Srinivasarao,Gunanathan, Chidambaram,Suresh, Eringathodi,Dastidar, Parthasarathi,Vir Jasra, Raksh
, p. 6307 - 6318 (2007/10/03)
A series of α-diazo carbonyl compounds having cyclopentanone, cyclohexanone and substituted cyclohexanone units with different tether lengths have been synthesized using diazomethane solution or methanesulphonyl azide. The above synthesized α-diazo carbon
