30319-92-7

Basic information

• Product Name: Phenanthridine, 5,6-dihydro-5-methyl-
• CAS NO: 30319-92-7
• Molecular Formula: C14H13N
• Molecular Weight: 195.264
• Mol File: 30319-92-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Phenanthridine, 5,6-dihydro-5-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Phenanthridine, 5,6-dihydro-5-methyl-(30319-92-7)
• EPA Substance Registry System: Phenanthridine, 5,6-dihydro-5-methyl-(30319-92-7)

Safety Data

• Hazardous Substances Data: 30319-92-7(Hazardous Substances Data)

Upstream product

• 5412-06-6 N-methyl phenanthridinium iodide 
• 64630-12-2 dihyrodeazaflavin 
• 172940-57-7 2-bromo-N-methyl-N-phenylbenzylamine 

Downstream Products

• 4217-54-3 9,10-dihydro-10-methylacridine 
• 69337-15-1 1,2-dihydro-2-methyl-5-nitroisoquinoline 
• 5412-06-6 N-methyl phenanthridinium iodide 
• 72594-76-4 3-cyano-1,4-dihydro-1-methylquinoline 
• 64630-12-2 dihyrodeazaflavin 
• 261-31-4 thioxanthene 
• 33718-28-4 5-methylphenanthridinium cation 

Relevant articles and documents

Switching between mono and doubly reduced odd alternant hydrocarbon: designing a redox catalyst

Since the early Hückel molecular orbital (HMO) calculations in 1950, it has been well known that the odd alternant hydrocarbon (OAH), the phenalenyl (PLY) system, can exist in three redox states: closed shell cation (12π e?), mono-reduced open shell neutral radical (13π e?) and doubly reduced closed shell anion (14π e?). Switching from one redox state of PLY to another leads to a slight structural change owing to its low energy of disproportionation making the electron addition or removal process facile. To date, mono-reduced PLY based radicals have been extensively studied. However, the reactivity and application of doubly reduced PLY species have not been explored so far. In this work, we report the synthesis of the doubly reduced PLY species (14π e?) and its application towards the development of redox catalysisviaswitching with the mono-reduced form (13π e?) for aryl halide activation and functionalization under transition metal free conditions without any external stimuli such as heat, light or cathodic current supply.