30362-06-2

Basic information

• Product Name: 2,4-dimethyl-6-(2-methylpropyl)-1,3,5-triazine
• Synonyms: 2-ISOBUTYL-4,6-DIMETHYL-S-TRIAZINE
• CAS NO: 30362-06-2
• Molecular Formula: C₉H₁₅N₃
• Molecular Weight: 165.2355
• Mol File: 30362-06-2.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 314.7°C at 760 mmHg
• Flash Point: 139.8°C
• Density: 0.984g/cm³
• Vapor Pressure: 0.000846mmHg at 25°C
• Refractive Index: 1.494
• CAS DataBase Reference: 2,4-dimethyl-6-(2-methylpropyl)-1,3,5-triazine(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-dimethyl-6-(2-methylpropyl)-1,3,5-triazine(30362-06-2)
• EPA Substance Registry System: 2,4-dimethyl-6-(2-methylpropyl)-1,3,5-triazine(30362-06-2)

Safety Data

• Hazardous Substances Data: 30362-06-2(Hazardous Substances Data)

Upstream product

• 823-94-9 2,4,6-trimethyl-s-triazine 
• 75-26-3 isopropyl bromide 
• 280-64-8 9-bora-bicyclo[3.3.1]nonane 
• 438200-16-9 2,4-dimethyl-6-(2-methyl-1-propenyl)-s-triazine 

Relevant articles and documents

Hydration with mercuric acetate and the reduction with 9-BBN-H of 2-(1-alkenyl)-4,6-dimethyl-s-triazines

Oxymercuration-demercuration of a double bond in conjugation with the 4,6-dimethyl-s-triazin-2-yl substituent as in alkenes la,b gave anti-Markovnikov regioselectivity, which is explained by the electron-withdrawing nature of the triazinyl substituent. However, hydroboration of the conjugated alkenes with 9-BBN-H gave the corresponding alkenes 5a-c under normal workup conditions with or without oxidation. With time and without workup the hydroboration of 1b gave spectral evidence for the formation of intermediates 9-13 resulting from the migration of the 9-BBN moiety from the α-carbon to a ring nitrogen with concurrent formation of an exocyclic double bond to an α-carbon of the ring. Hydrolysis of the intermediates gave 5a-c. A possible mechanism involving successive allylic rearrangements is presented.