3041-57-4Relevant articles and documents
Boron trifluoride-tetrahydrofuran complex: A superior trigger for the Yamaguchi-Hirao alkylation of lithio-acetylides by epoxides
Evans, Ann B,Knight, David W
, p. 6947 - 6948 (2001)
Use of BF3·THF complex in place of the usual BF3·OEt2 analogue in the Yamaguchi-Hirao alkylation of lithio-acetylides 2 by monosubstituted epoxides 3 gives consistently superior isolated yields (ca. 90%) of homopropargylic
AN EFFICIENT METHOD FOR THE ALKYNYLATION OF OXIRANES USING ALKYNYL BORANES
Yamaguchi, Masahiko,Hirao, Ichiro
, p. 391 - 394 (2007/10/02)
Alkynyl boranes, generated in situ from lithium acetylides and boron trifluoride etherate, were found to react with oxiranes under mild reaction conditions to afford β-hydroxyacetylenes in high yields.