304436-88-2Relevant academic research and scientific papers
Isomerization of 2-methyl-3-butyn-2-ol into prenal: Mechanistic observations on tricomponent catalyst systems of the type Ti(OR)4-CuCl-R'CO2H. Crystal structure of [CuCl(Me2C(OH)C≡CH)]4
Lorber, Christian Y,Youinou, Marie-Thérèse,Kress, Jacky,Osborn, John A
, p. 1693 - 1698 (2000)
The mechanism of the title catalytic system was investigated, in particular by synthesizing several compounds that model the postulated metal-oxo-propargyloxo intermediates, such as [Ti(μ-O)(O-Bu')(O2CTol)]2 (Tol = p-MeC6H
