304669-50-9Relevant academic research and scientific papers
A new efficient tetraphosphine/palladium catalyst for the Heck reaction of aryl halides with styrene or vinylether derivatives
Feuerstein, Marie,Doucet, Henri,Santelli, Maurice
, p. 2191 - 2194 (2007/10/03)
cis,cis,cis-1,2,3,4-Tetrakis(diphenylphosphinomethyl)cyclopentane/[PdCl(C 3H5)]2 system efficiently catalyses the Heck reaction of aryl halides with styrene and vinylether derivatives. High turnover numbers can be obtained for the reaction of several aryl halides with styrene and styrene derivatives. Lower turnover numbers have been observed in the presence of vinylethers.
Mild and general cross-coupling of (α-alkoxyvinyl)silanols and -silyl hydrides
Denmark, Scott E.,Neuville, Luc
, p. 3221 - 3224 (2007/10/03)
(Matrix presented) (α-Alkoxyvinyl)silanols and (α-alkoxyvinyl)silyl hydrides are efficiently converted to aryl vinyl ethers by a palladium(0)-catalyzed cross-coupling reaction with aryl halides in the presence of tetrabutylammonium fluoride or hydroxide.
α-Regioselectivity in Palladium-Catalyzed Arylation of Acyclic Enol Ethers
Cabri, Walter,Candiani, Ilaria,Bedeschi, Angelo,Penco, Sergio,Santi, Roberto
, p. 1481 - 1486 (2007/10/02)
Regioselective α-arylation of acyclic enol ethers by aryl trifluoromethanesulfonates, aryl bromide, aryl iodides, and aroyl chlorides is described.The outcome of the reaction proved to be dependent from the relationship between ligand and counterion in the oxidative complex.
