30483-86-4Relevant academic research and scientific papers
Synthesis of spiroacetal pheromones via metalated hydrazones
Enders,Dahmen,Dederichs,Gatzweiler,Weuster
, p. 1013 - 1019 (2007/10/02)
The synthesis of simple alkyl substituted spiroacetals by α,α'-alkylation of metalated acetone dimethylhydrazone with appropriate electrophiles and subsequent acid catalyzed cleavage and ring closure of the products is described.
Chemistry of Fruit Flies: Composition of the Male Rectal Gland Secretions of some Species of South-East Asian Dacinae. Re-examination of Dacus Cucurbitae (Melon Fly)
Perkins, Michael V.,Kitching, William,Drew, Richard A. I.,Moore, Christopher J.,Koenig, Wilfried A.
, p. 1111 - 1117 (2007/10/02)
The major components of the rectal glandular secretions of male Dacus (Bactrocera) umbrosus (jack fruit fly), D. (Bactrocera) nigrotibialis, D. (Bactrocera) albistrigatus, D. (Zeugodacus) tau and D. (Zeugodacus) sp. (taxonomically similar to D. tau) have been identified.Alcohols, spiroacetals, and amides are the dominant components.The major component in the rectal gland secretion of Dacus (Zeugodacus) cucurbitae (melon fly) is shown to be ethyl 4-hydroxybenzoate and not 2-ethoxybenzoic acid.
SPIROACETALS FROM ACETONE AND OXIRANES - A SIMPLE ROUTE TO OPTICALLY ACTIVE 1,6-DIOXASPIRONONANE-PHEROMONES
Enders, D.,Dahmen, W.,Dederichs, E.,Weuster, P.
, p. 1235 - 1242 (2007/10/02)
A new and efficient synthesis of 1,6-dioxaspirononane-spiroacetals, starting from the simple building blocks acetone and oxiranes is described.
2,9-DIOXABICYCLONONAN-DARSTELLUNG, MASSENSPEKTROSKOPIE UND UMLAGERUNG EINES NEUEN HETEROCYCLISCHEN SYSTEMS
Francke, Wittko,Reith, Wolfgang
, p. 2029 - 2032 (2007/10/02)
Nine different methyl-substituted compounds of a new acetal system 5 are synthesized from 4-(5-methyl-2-furyl)alkanoles 1 and are rearranged to ketones 6; mass spectroscopic fragmentation patterns are described.
