304904-74-3Relevant academic research and scientific papers
Hetero Diels-Alder reaction of vinyl allenes and aldehydes. An experimental and computational study
Regas, David,Ruiz, Juan M.,Afonso, Maria M.,Palenzuela, J. Antonio
, p. 9153 - 9164 (2006)
(Chemical Equation Presented) The hetero Diels-Alder reaction of vinyl allenes and aldehydes in the presence of a Lewis acid has been studied both experimentally and theoretically. Differently substituted vinyl allenes and aldehydes were used to obtain in
Vinyl-allenes as dienes in the Lewis acid-mediated hetero Diels-Alder reaction with aldehydes
Regas,Afonso,Galindo,Palenzuela
, p. 6781 - 6784 (2007/10/03)
The Lewis acid-mediated, hetero Diels-Alder reaction of a vinyl-allene system with aldehydes as heterodienophiles has been carried out. In the cases studied, only two cycloadducts have been obtained, which correspond to the endo (major compound) and exo (minor compound) approach of the aldehyde through the less hindered face of the dienic system. (C) 2000 Elsevier Science Ltd.
