3053-13-2Relevant academic research and scientific papers
Synthesis and NMR studies of methyl 3-O-[(R)- and (S)-1-carboxyethyl]-α-D-gluco-, galacto- and manno- pyranosides
Andersson, Lars,Kenne, Lennart
, p. 157 - 164 (1998)
The title compounds were prepared by condensation of a suitably protected monosaccharide and (R)- or (S)-2-chloropropionic acid followed by removal of the protecting groups. Characterisation by 1H and 13C NMR spectroscopy and NOE difference experiments revealed both chemical shift and enhancement differences between the diastereomers which could be used in determination of the absolute configuration of the 1-carboxyethyl group. Copyright (C) 1998 Elsevier Science Ltd.
ALKYLATION OF METHYL 4,6-O-BENZYLIDENE-α-D-GALACTOPYRANOSIDE
Grishkovets, V. I.,Chirva, V. Ya.
, p. 25 - 28 (2007/10/02)
The partial alkylation of methyl 4,6-benzylidene-α-D-galactopyranoside in dimethylformamide and dimethyl sulfoxide in the presence of barium oxide and hydroxide is described.It has been shown that methylation and benzylation lead predominantly to the 3-al
