305635-94-3

Upstream product

• 57-88-5 cholesterol 
• 151419-76-0 4'-(10-undecen-1-yloxy)-1,1'-biphenyl-4-carboxylic acid 
• 7766-50-9 1-undecen-11-ylbromide 
• 51148-67-5 10-undecen-1-yl p-toluenesulfonate 
• 194148-49-7 4'-(10-undecen-1-yloxy)-1,1'-biphenyl-4-carbonyl chloride 
• 112-43-6 10-Undecen-1-ol 
• 58574-03-1 4'-Hydroxybiphenyl-4-carboxylic acid 

Downstream Products

• 872438-13-6 4'-[11-(1,1,3,3-Tetramethyl-disiloxanyl)-undecyloxy]-biphenyl-4-carboxylic acid (3S,8S,9S,10R,13R,14S,17R)-17-((R)-1,5-dimethyl-hexyl)-10,13-dimethyl-2,3,4,7,8,9,10,11,12,13,14,15,16,17-tetradecahydro-1H-cyclopenta[a]phenanthren-3-yl ester 

Relevant academic research and scientific papers

Chiral nematic liquid crystalline copolymers as stationary phase materials in capillary gas chromatography

A new series of liquid crystalline polysiloxanes with a very wide range of mesomorphic temperatures has been prepared. They contain 4-cholesteryl-(10- undecen-1-yloxy) biphenyl-4'-carboxylate mesogenic and 4-biphenyl-4'- allyloxybenzoate mesogenic side groups displaying enantiotropic nematic and chiral nematic phases. The mesomorphic polysiloxane specimen with the widest temperature range was used as the stationary phase in a gas chromatography capillary column and it showed unique separation properties for polycyclic aromatic compounds.

Cholesteric silatranes

Most liquid crystals with a C3 symmetry have so far been discotic systems, e.g., triphenylenes. In the context of calamitic systems research has concentrated on triptycenes and to a lesser extend on silatranes. In this contribution we report our investigations of cholesteric silatrane systems, which have been obtained by connecting a tribenzylsilatrane core to cholesteric groups via alkyl and siloxane spacer groups.