30595-49-4

Usage

Appearance

Yellow crystalline solid

Molecular Weight

265.14 g/mol

Primary Use

Explosives and propellants

Sensitivity

Highly sensitive

Power

Powerful

Reactivity

Highly reactive

Explosive Nature

Yes

Nitrogen Content

High

Potential Energy

Similar to cyclotetramethylene-tetranitramine (HMX)

Safety Precautions

Handle with extreme caution, store properly to prevent accidental detonation.

Upstream product

• 27200-08-4 4-nitro-2-phenyl-2H-1,2,3-triazole 
• 51039-49-7 2-phenyl-2H-[1,2,3]triazole 
• 100-63-0 phenylhydrazine 

Downstream Products

• 119-27-7 2,4-dinitroanisole 
• 84406-63-3 4⁽⁵⁾-nitro-1,2,3-triazole 

Relevant academic research and scientific papers

Sensitive Energetics from the N-Amination of 4-Nitro-1,2,3-Triazole

Energetic N-amino-C-nitro compounds 1-amino-4-nitro-1,2,3-triazole and 2-amino-4-nitro-1,2,3-triazole are characterized for the first time as energetic materials. These compounds were characterized chemically by nuclear magnetic resonance (NMR), Infrared

Ionic liquids based on azolate anions

Compartmentalized molecular level design of new energetic materials based on energetic azolate anions allows for the examination of the effects of both cation and anion on the physiochemical properties of ionic liquids. Thirty one novel salts were synthesized by pairing diverse cations (tetraphenylphosphonium, ethyltriphenylphosphonium, /V-phenyl pyridinium, 1butyl-3-methylimidazolium, tetramethyl-, tetraethyl-, and tetrabutylammonium) with azolate anions (5-nitrobenzimidazolate, 5-nitrobenzotriazolate, 3,5-dinitro-1,2,4-triazolate, 2,4-dinitroimidazolate, 4-nitro-l ,2,3-triazolate, 4,5-dinitroimidazolate, 4,5-dicyanoimidazolate, 4-nitroimidazolate, and tetrazolate). These salts have been characterized by DSC, TGA, and single crystal X-ray crystallography. The azolates in general are surprisingly stable in the systems explored. Ionic liquids were obtained with all combinations of the l-butyl-3-methylimidazoli-um cation and the heterocyclic azolate anions studied, and with several combinations of tetraethyl- or tetrabutylammonium cations and the azolate anions. Favorable structure-property relationships were most often achieved when changing from 4- and 4,5-disubstituted anions to 3,5- and 2,4-disubstituted anions. The most promising anion for use in energetic ionic liquids of those studied here, was 3,5-dinitro-l ,2,4-triazolate, based on its contributions to the entire set of target properties.

Nitration of 4-Substituted 2-Phenyl-1,2,3-triazoles

Substituent in position 4 of the heteroring influences the nitration of 2-phenyl-1,2,3-triazoles. Electron-donor substituents favor nitration at the heteroring.