30614-67-6

Basic information

• Product Name: 3-FURYLMETHYL ACETATE
• Synonyms: 3-FURYLMETHYL ACETATE
• CAS NO: 30614-67-6
• Molecular Formula: C₇H₈O₃
• Molecular Weight: 140.14
• Mol File: 30614-67-6.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 180.5°C at 760 mmHg
• Flash Point: 72.2°C
• Appearance: /
• Density: 1.12g/cm³
• Vapor Pressure: 0.893mmHg at 25°C
• Refractive Index: 1.464
• CAS DataBase Reference: 3-FURYLMETHYL ACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-FURYLMETHYL ACETATE(30614-67-6)
• EPA Substance Registry System: 3-FURYLMETHYL ACETATE(30614-67-6)

Safety Data

• Hazardous Substances Data: 30614-67-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C7H8O3/c1-6(8)10-5-7-2-3-9-4-7/h2-4H,5H2,1H3

Upstream product

• 26214-65-3 furan-3-carbonyl chloride 
• 614-98-2 ethyl 3-furancarboxylate 
• 488-93-7 3-Furoic acid 

Downstream Products

• 4412-91-3 furan-3-methanol 
• 1332480-09-7 C₁₉H₁₉NO₆ 

Relevant articles and documents

Cycloaddition of C-3 substituted furans. Stereoselectivity induced by coordination effects

Several C-3 substituted furans with chelating groups have been reacted with 2,3-dibromo-3-pentanone in the presence of a reducing metal, resulting in the formation of [4+3]-cycloadducts with complete cis-trans and endo-exo diastereoselectivity and in excellent yield. A certain variability of the conversion and reaction yield could be observed, when changing the reaction conditions, but in all cases the stereoselectivity was complete, compared to that of C-3 substituted furans with non-chelating groups. Also, a general method of assignment of stereochemistry of cycloadducts has been established by NMR, considering diagnostic patterns of signals with different multiplicity and chemical shifts depending on the stereochemistry of diastereomeric cycloadducts.