306283-78-3

Upstream product

• 56222-36-7 (E,E)-N¹,N²-bis(2,4,6-trimethylphenyl)ethane-1,2-diimine 
• 306283-68-1 2,4-Dichloro-1,3-dimesityl-1,3,2-diazaphospholene 
• 1493-13-6 trifluorormethanesulfonic acid 
• 306283-72-7 4-chloro-1,3-bis-(2,4,6-trimethyl-phenyl)-2,3-dihydro-1H-[1,3,2]diazaphosphole 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 

Downstream Products

• 333303-94-9 trans-[(2,2'-bipyridine)-dicarbonyl-(1,3-dimesityl-4-chlorodiazaphospholenium)-triflato-tungsten⁽⁰⁾] 
• 333303-96-1 fac-[(2,2'-bipyridine)-tricarbonyl-(1,3-dimesityl-4-chlorodiazaphospholenium)-tungsten⁽⁰⁾] triflate 
• 333303-93-8 trans-[(2,2'-bipyridine)-dicarbonyl-(1,3-dimesityl-4-chlorodiazaphospholenium)-triflato-molybdenum⁽⁰⁾] 

Relevant academic research and scientific papers

Novel aspects of phosphorus analogues of arduengo carbenes: From very stable phosphenium ions to umpolung of P-H bonds

According to the results of structural and computational studies, P-halogeno-diazaphospholenes are not ionic but feature weak and polar covalent P-X bonds. Similar bond weakening effects which are attributable to l.p. (N)-σ*(P-X) hyperconjugation were als

Stability and electrophilicity of phosphorus analogues of Arduengo carbenes - An experimental and computational study

A variety of differently substituted 1,3,2-diazaphospholenium salts and P-halogeno-1,3,2-diazaphospholenes (X = F, Cl, Br) were synthesized, and their molecular structures, bonding situation; and Lewis acid properties were characterized by experimental (s