30648-76-1

Basic information

• Product Name: exo-bicyclo[3.1.0]hexane-6-carboxylate methyl ester
• CAS NO: 30648-76-1
• Molecular Weight: 140.182
• Mol File: 30648-76-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: exo-bicyclo[3.1.0]hexane-6-carboxylate methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: exo-bicyclo[3.1.0]hexane-6-carboxylate methyl ester(30648-76-1)
• EPA Substance Registry System: exo-bicyclo[3.1.0]hexane-6-carboxylate methyl ester(30648-76-1)

Safety Data

• Hazardous Substances Data: 30648-76-1(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 4971-24-8 1α,5α,6α-bicyclo[3.1.0]hexane-6-carboxylic acid 
• 142-29-0 cyclopentene 
• 72229-06-2 ethyl bicyclo<3.1.0>hexane-6-carboxylate 

Relevant articles and documents

Activation energies for the 1,2-carbon migration of ring-fused cyclopropylchlorocarbenes

Fused-ring cyclopropylchlorocarbenes 2 and 3 ring expand to fused-ring chlorocyclobutenes 10 and 11, respectively, with activation energies of 3-4 kcal/mol and activation entropies of ～-20 e.u. Carbon tunneling appears to be unimportant at low temperatures.